Reconsideration of the dielectric properties response of concentration dependence of aqueous urea solution at the microwave frequency

被引:1
|
作者
Gu, Yang [1 ]
Jia, Guo-Zhu [1 ]
机构
[1] Sichuan Normal Univ, Coll Phys & Elect Engn, Chengdu, Peoples R China
基金
中国国家自然科学基金;
关键词
Dielectric property response; microwave frequency; cooperative interaction; MOLECULAR-DYNAMICS SIMULATIONS; HYDROGEN-BOND DYNAMICS; WATER MIXTURES; RELAXATION; PERMITTIVITY; SPECTROSCOPY; STABILIZATION; TEMPERATURE; SOLVENTS; BEHAVIOR;
D O I
10.1080/00319104.2015.1079192
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
In this paper, we investigate the dielectric properties of aqueous urea solution over the frequency range 200 MHz-20 GHz. We reveal the single nature of urea- water cooperative interaction and draw a profile of the overview that urea- water cooperative interaction plays a dominating role in the aqueous urea solution system using Cole- Cole analysis. The self- diffusion coefficient is related to the concentration of the urea aqueous solution. The decay of the effective number of water molecules bound to the urea molecules with its concentration and the urea perturb the water structure beyond the first hydration shell, which is confirmed in the aqueous urea solution system. And the relation between tau and a may be utilised widely to measure the urea concentration for a microwave biosensor technique.
引用
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页码:258 / 267
页数:10
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