A nanostructured CeO2 promoted Pd/α-alumina diethyl oxalate catalyst with high activity and stability

被引:19
|
作者
Jin, Erlei [1 ]
He, Leilei [1 ]
Zhang, Yulong [2 ]
Richard, Anthony R. [1 ]
Fan, Maohong [1 ,3 ]
机构
[1] Univ Wyoming, Dept Chem & Petr Engn, Laramie, WY 82071 USA
[2] Western Res Inst, Laramie, WY 82070 USA
[3] Univ Wyoming, Sch Energy Resources, Laramie, WY 82071 USA
关键词
CO COUPLING REACTION; CARBON-MONOXIDE; PD-FE/ALPHA-AL2O3; CATALYST; ETHYLENE-GLYCOL; PALLADIUM; NANOCATALYST; HYDROGEN; KINETICS; PROGRESS; NITRITE;
D O I
10.1039/c4ra08170f
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
A Pd/alpha-Al2O3 nanocatalyst was synthesized and investigated as a catalyst for CO oxidative coupling to diethyl oxalate and CeO2 was used as a promoter. With the highest activity and stability found so far, great CO conversion and diethyl oxalate selectivity were achieved due to the addition of CeO2.
引用
收藏
页码:48901 / 48904
页数:4
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