Thermodynamic factor in diffusion in the non-stoichiometric compounds Ni3Ga and Pt3In

被引:0
|
作者
Yuan, WX [1 ]
Wu, XH
Qiao, ZY
Semenova, O
Ipser, H
机构
[1] Univ Sci & Technol Beijing, Appl Sci Sch, Beijing 100083, Peoples R China
[2] Univ Sci & Technol Beijing, Met Sch, Beijing 100083, Peoples R China
[3] Univ Vienna, Inst Inorgan Chem, A-1090 Vienna, Austria
关键词
thermodynamic factor; diffusion; Ni3Ga; Pt3In;
D O I
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中图分类号
T [工业技术];
学科分类号
08 ;
摘要
The thermodynamic factor in diffusion in the L1(2)-type non-stoichiometric intermetallic compounds Ni3Ga and Pt3In was derived from the experimentally measured activities of Ga and In, respectively. The results show that the thermodynamic factor in diffusion in the Ni3Ga and Pt3In compounds exhibits the maximum near the stoichiometric composition with the variation of composition over the compound region. The values indicate strong interaction between Ni and Ga atoms, as well as Pt and In atoms, respectively, as expected in ordered alloys.
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页码:186 / 189
页数:4
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