Highly selective synthesis of acetylenic alcohols promoted by metallic dysprosium in the presence of mercuric chloride

被引：5
|
作者：
Li, ZM [1 ]
Jia, Y [1 ]
Zhou, JY [1 ]
机构：
[1] Fudan Univ, Dept Chem, Shanghai 200433, Peoples R China
来源：
SYNTHETIC COMMUNICATIONS | 2000年 / 30卷 / 14期
基金：
中国国家自然科学基金;
关键词：
D O I：
10.1080/00397910008087415
中图分类号：
O62 [有机化学];
学科分类号：
070303 ; 081704 ;
摘要：
Promoted by metallic dysprosium, carbonyl compounds react smoothly with propargyl bromide to afford the corresponding homopropargylic alcohols in good to excellent yields without observation of allenic alcohols. In addition, this reaction is regioselective and chemoselective.
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页码：2515 / 2524
页数：10
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