Anchored Pd complex in MCM-41 and MCM-48: Novel heterogeneous catalysts for hydrocarboxylation of aryl olefins and alcohols

被引：169
|
作者：
Mukhopadhyay, K [1 ]
Sarkar, BR [1 ]
Chaudhari, RV [1 ]
机构：
[1] Natl Chem Lab, Homogeneous Catalysis Div, Pune 411008, Maharashtra, India
来源：
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY | 2002年 / 124卷 / 33期
关键词：
D O I：
10.1021/ja025991q
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
We report here, for the first time, synthesis of anchored Pd complexes in mesoporous supports such as MCM-41 and MCM-48 as true heterogeneous catalysts for hydrocarboxylation of aryl olefins and alcohols to give excellent conversion (∼100%) and regioselectivity (∼99%) for 2-arylpropionic acids. The catalysts were characterized by powder-XRD, 31PCP-MAS NMR, FT-IR, TEM, XPS and ICP-AES. Recycle studies with these anchored Pd mesoporous catalysts were performed to confirm true heterogeneity. Copyright © 2002 American Chemical Society.
引用
收藏
页码：9692 / 9693
页数：2
相关论文
共 50 条
  • [31] Templated synthesis and structural study of densely packed metal nanostructures in MCM-41 and MCM-48
    Yang, CM
    Sheu, HS
    Chao, KJ
    ADVANCED FUNCTIONAL MATERIALS, 2002, 12 (02) : 143 - 148
  • [32] Heterogeneous catalytic ozonation of clofibric acid using Ce/MCM-48: Preparation, reaction mechanism, comparison with Ce/MCM-41
    Li, Shangyi
    Tang, Yiming
    Chen, Weirui
    Hu, Zhe
    Li, Xukai
    Li, Laisheng
    JOURNAL OF COLLOID AND INTERFACE SCIENCE, 2017, 504 : 238 - 246
  • [33] Ethylene oligomerization over Ni-containing mesostructured catalysts with MCM-41, MCM-48 and SBA-15 topologies
    Lallemand, M.
    Finiels, A.
    Fajula, F.
    Hulea, V.
    FROM ZEOLITES TO POROUS MOF MATERIALS: THE 40TH ANNIVERSARY OF INTERNATIONAL ZEOLITE CONFERENCE, PROCEEDINGS OF THE 15TH INTERNATIONAL ZEOLITE CONFERENCE, 2007, 170 : 1863 - 1869
  • [34] Pd Functionalized MCM-41 Catalysts for Suzuki Reactions
    Nevin Gürbüz
    Sema Vural
    Sedat Yaşar
    İsmail Özdemir
    Turgay Seçkin
    Journal of Inorganic and Organometallic Polymers and Materials, 2010, 20 : 19 - 25
  • [35] Pd Functionalized MCM-41 Catalysts for Suzuki Reactions
    Gurbuz, Nevin
    Vural, Sema
    Yasar, Sedat
    Ozdemir, Ismail
    Seckin, Turgay
    JOURNAL OF INORGANIC AND ORGANOMETALLIC POLYMERS AND MATERIALS, 2010, 20 (01) : 19 - 25
  • [36] Metalloporphyrins catalysts anchored on MCM-41 for the selective oxidation of cycloexene
    Costa, Andreia Alves
    de Macedo, Julio Lemos
    Braga, Valdeilson Souza
    Dias, Jose Alves
    Loureiro Dias, Silvia Claudia
    Santos, Marcello Moreira
    ABSTRACTS OF PAPERS OF THE AMERICAN CHEMICAL SOCIETY, 2007, 233
  • [37] Synthesis, characterization, and photocatalytic activity of MCM-41 and MCM-48 impregnated with CeO2 nanoparticles
    Hamid Reza Pouretedal
    Mina Ahmadi
    International Nano Letters, 2012, 2 (1)
  • [38] Influence of pH on the sorption behaviour of uranyl ions in mesoporous MCM-41 and MCM-48 molecular sieves
    Vidya, K
    Gupta, NM
    Selvam, P
    MATERIALS RESEARCH BULLETIN, 2004, 39 (13) : 2035 - 2048
  • [39] Hydrosilylation of olefins over rhodium complex anchored over thioether-functionalized MCM-41
    Lig Fang Zha
    Chinese Chemical Letters, 2010, 21 (11) : 1310 - 1313
  • [40] Manganese (III) salen complex anchored onto MCM-41 as catalyst for the aerobic epoxidation of olefins
    Zhang, Yaran
    Zhao, Jiquan
    He, Leqin
    Zhao, Dongmin
    Zhang, Songmei
    MICROPOROUS AND MESOPOROUS MATERIALS, 2006, 94 (1-3) : 159 - 165
12345