New version of the Rayleigh-Schrodinger perturbation theory:: Examples

被引:0
|
作者
Kalhous, M
Skála, L
Zamastil, J
Cízek, J
机构
[1] Charles Univ Prague, Fac Math & Phys, CR-12116 Prague 2, Czech Republic
[2] Univ Waterloo, Waterloo, ON N2L 3G1, Canada
关键词
D O I
10.1002/qua.20041
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
It has been shown in our preceding papers that the linear dependence of the perturbation wave functions on the perturbation energies makes possible to calculate the exact perturbation energies from the values of the perturbation wave functions corresponding to arbitrarily chosen trial perturbation energies. The resulting version of the perturbation theory is very simple and can be used at large orders. In this paper, this method is applied to a few problems and its numerical properties are discussed. (C) 2004 Wiley Periodicals, Inc.
引用
收藏
页码:325 / 335
页数:11
相关论文
共 50 条