A turn-on and reversible Schiff-base fluorescence sensor for Al3+ ion

被引:24
|
作者
Lu, Cheng-Yi [1 ]
Liu, Yen-Wen [1 ]
Hung, Pei-Ju [1 ]
Wan, Chin-Feng [2 ]
Wu, An-Tai [1 ]
机构
[1] Natl Changhua Univ Educ, Dept Chem, Changhua 50058, Taiwan
[2] Chung Shan Med Univ, Sch Appl Chem, Taichung 40201, Taiwan
关键词
Chemosensor; Fluorescence; Turn-on; Schiff-base; PHOTOINDUCED ELECTRON-TRANSFER; SELECTIVE FLUORESCENT; ALUMINUM IONS; ENHANCED SENSOR; HYBRID LIGAND; CHEMOSENSOR; SCAFFOLD; PROBE; HG2+; DERIVATIVES;
D O I
10.1016/j.inoche.2013.06.005
中图分类号
O61 [无机化学];
学科分类号
070301 ; 081704 ;
摘要
A simple Schiff-base receptor 1 was prepared. It exhibits an "off-on-type" mode with high sensitivity in the presence of Al3+. The receptor 1 exhibited a high association constant with submicromolar detection for Al3+ in EtOH-H2O (95:5 v/v) solution. The addition of EDTA quenches the fluorescence of receptor 1 center dot Al3+ complex offering receptor 1 as a reversible chemosensor. Crown Copyright (C) 2013 Published by Elsevier B.V. All rights reserved.
引用
收藏
页码:273 / 275
页数:3
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