Microstructural analysis of 9.7% efficient Cu2ZnSnSe4 thin film solar cells

被引：22

作者：

Buffiere, M. ^{[1
,2
]}

Brammertz, G. ^{[3
,4
]}

Batuk, M. ^{[5
]}

Verbist, C. ^{[5
]}

Mangin, D. ^{[6
]}

Koble, C. ^{[7
]}

Hadermann, J. ^{[5
]}

Meuris, M. ^{[3
,4
]}

Poortmans, J. ^{[1
,2
,4
]}

机构：

[1] Katholieke Univ Leuven, Dept Elect Engn ESAT, B-3001 Heverlee, Belgium

[2] Imec Partner Solliance, B-3001 Leuven, Belgium

[3] Imec Div IMOMEC Partner Solliance, B-3590 Diepenbeek, Belgium

[4] Hasselt Univ, Inst Mat Res IMO, B-3590 Diepenbeek, Belgium

[5] Univ Antwerp, Electron Microscopy Mat Sci EMAT, B-2020 Antwerp, Belgium

[6] Univ Lorraine, Inst Jean Lamour, F-54011 Nancy, France

[7] Helmholtz Zentrum Berlin Mat & Energie GmbH, D-14109 Berlin, Germany

来源：

APPLIED PHYSICS LETTERS | 2014年 / 105卷 / 18期

关键词：

OPTICAL-PROPERTIES; BACK CONTACT; MODULES;

D O I：

10.1063/1.4901401

中图分类号：

O59 [应用物理学];

学科分类号：

摘要：

This work presents a detailed analysis of the microstructure and the composition of our record Cu2ZnSnSe4 (CZTSe)-CdS-ZnO solar cell with a total area efficiency of 9.7%. The average composition of the CZTSe crystallites is Cu1.94Zn1.12Sn0.95Se3.99. Large crystals of ZnSe secondary phase (up to 400 nm diameter) are observed at the voids between the absorber and the back contact, while smaller ZnSe domains are segregated at the grain boundaries and close to the surface of the CZTSe grains. An underlying layer and some particles of CuxSe are observed at the Mo-MoSe2-Cu2ZnSnSe4 interface. The free surface of the voids at the back interface is covered by an amorphous layer containing Cu, S, O, and C, while the presence of Cd, Na, and K is also observed in this region. (C) 2014 AIP Publishing LLC.

引用

页数：5

共 50 条

[31] Preparation and Analysis of Sputtered Cu2ZnSnSe4 Thin Films
Kuo, Dong-Hau
Wu, Hsien-Pen
ADVANCED MATERIALS RESEARCH II, PTS 1 AND 2, 2012, 463-464 : 602 - 606
[32] Cu2ZnSnSe4 thin-film solar cells fabricated using Cu2SnSe3 and ZnSe bilayers
Kim, Kang Min
Liao, Kuang Hsiang
Tampo, Hitoshi
Shibata, Hajime
Niki, Shigeru
APPLIED PHYSICS EXPRESS, 2015, 8 (04)
[33] Influence of Substrate Temperature on Cu2ZnSnSe4 Thin Film Solar Cells Fabricated by Co-evaporation Process
Sun D.
Li Y.-L.
Wang L.-Q.
Zhang Y.-H.
Liu H.
Guo X.-J.
Chi Y.-D.
Zhang L.
Faguang Xuebao/Chinese Journal of Luminescence, 2019, 40 (03): : 334 - 339
[34] Cu2ZnSnSe4 thin film solar cells based on a single-step co-evaporation process
Jung, Sunghun
Gwak, Jihye
Yun, Jae Ho
Ahn, Sejin
Nam, Dahyun
Cheong, Hyeonsik
Ahn, Seungkyu
Cho, Ara
Shin, KeeShik
Yoon, KyungHoon
THIN SOLID FILMS, 2013, 535 : 52 - 56
[35] Ge-incorporated Cu2ZnSnSe4 thin-film solar cells with efficiency greater than 10%
Kim, Shinho
Kim, Kang Min
Tampo, Hitoshi
Shibata, Hajime
Matsubara, Koji
Niki, Shigeru
SOLAR ENERGY MATERIALS AND SOLAR CELLS, 2016, 144 : 488 - 492
[36] Surface and interface engineering for highly efficient Cu2ZnSnSe4 thin-film solar cells via in situ formed ZnSe nanoparticles
Yoo, Hyesun
Park, Jongsung
Suryawanshi, Mahesh P.
Lee, Jiwon
Kim, JunHo
Eom, Kiryung
Seo, Hyungtak
Jung, HyoRim
Kim, Dong Myeong
Shin, Seung Wook
Kim, Jin Hyeok
JOURNAL OF MATERIALS CHEMISTRY A, 2021, 9 (09) : 5442 - 5453
[37] Effect of Cu content and temperature on the properties of Cu2ZnSnSe4 solar cells
Sahayaraj, Sylvester
Brammertz, Guy
Buffiere, Marie
Meuris, Marc
Vleugels, Jef
Poortmans, Jef
EPJ PHOTOVOLTAICS, 2016, 7
[38] Improving the open-circuit voltage of Cu2ZnSnSe4 thin film solar cells via interface passivation
Kim, Jekyung
Park, Sanghyun
Ryu, Sangwoo
Oh, Jihun
Shin, Byungha
PROGRESS IN PHOTOVOLTAICS, 2017, 25 (04): : 308 - 317
[39] Characterization of Ag-doped Cu2ZnSnSe4 bulks material and their application as thin film semiconductor in solar cells
Saragih, Albert Daniel
Wubet, Walelign
Abdullah, Hairus
Abay, Angaw Kelemework
Kuo, Dong-Hau
MATERIALS SCIENCE AND ENGINEERING B-ADVANCED FUNCTIONAL SOLID-STATE MATERIALS, 2017, 225 : 45 - 53
[40] Coevaporation of Cu2ZnSnSe4 thin films
Redinger, Alex
Siebentritt, Susanne
APPLIED PHYSICS LETTERS, 2010, 97 (09)

← 1 2 3 4 5 →