Microstructural analysis of 9.7% efficient Cu2ZnSnSe4 thin film solar cells

被引：22

作者：

Buffiere, M. ^{[1
,2
]}

Brammertz, G. ^{[3
,4
]}

Batuk, M. ^{[5
]}

Verbist, C. ^{[5
]}

Mangin, D. ^{[6
]}

Koble, C. ^{[7
]}

Hadermann, J. ^{[5
]}

Meuris, M. ^{[3
,4
]}

Poortmans, J. ^{[1
,2
,4
]}

机构：

[1] Katholieke Univ Leuven, Dept Elect Engn ESAT, B-3001 Heverlee, Belgium

[2] Imec Partner Solliance, B-3001 Leuven, Belgium

[3] Imec Div IMOMEC Partner Solliance, B-3590 Diepenbeek, Belgium

[4] Hasselt Univ, Inst Mat Res IMO, B-3590 Diepenbeek, Belgium

[5] Univ Antwerp, Electron Microscopy Mat Sci EMAT, B-2020 Antwerp, Belgium

[6] Univ Lorraine, Inst Jean Lamour, F-54011 Nancy, France

[7] Helmholtz Zentrum Berlin Mat & Energie GmbH, D-14109 Berlin, Germany

来源：

APPLIED PHYSICS LETTERS | 2014年 / 105卷 / 18期

关键词：

OPTICAL-PROPERTIES; BACK CONTACT; MODULES;

D O I：

10.1063/1.4901401

中图分类号：

O59 [应用物理学];

学科分类号：

摘要：

This work presents a detailed analysis of the microstructure and the composition of our record Cu2ZnSnSe4 (CZTSe)-CdS-ZnO solar cell with a total area efficiency of 9.7%. The average composition of the CZTSe crystallites is Cu1.94Zn1.12Sn0.95Se3.99. Large crystals of ZnSe secondary phase (up to 400 nm diameter) are observed at the voids between the absorber and the back contact, while smaller ZnSe domains are segregated at the grain boundaries and close to the surface of the CZTSe grains. An underlying layer and some particles of CuxSe are observed at the Mo-MoSe2-Cu2ZnSnSe4 interface. The free surface of the voids at the back interface is covered by an amorphous layer containing Cu, S, O, and C, while the presence of Cd, Na, and K is also observed in this region. (C) 2014 AIP Publishing LLC.

引用

页数：5

共 50 条

[1] Weatherability of Cu2ZnSnSe4 thin film solar cells on diverse substrates
Lai, Fang-, I
Yang, Jui-Fu
Chen, Wei-Chun
Hsu, Yu-Chao
Kuo, Shou-Yi
SOLAR ENERGY, 2020, 195 (195) : 626 - 635
[2] Efficient Bifacial Cu2ZnSnSe4 Solar Cells
Espindola-Rodriguez, M.
Sanchez, Y.
Lopez-Marino, S.
Xie, H.
Izquierdo-Roca, V.
Sylla, D.
Neuschitzer, M.
Vigil-Galan, O.
Saucedo, E.
Placidi, M.
2015 IEEE 42ND PHOTOVOLTAIC SPECIALIST CONFERENCE (PVSC), 2015,
[3] Temperature dependent electrical characterization of thin film Cu2ZnSnSe4 solar cells
Kask, E.
Krustok, J.
Giraldo, S.
Neuschitzer, M.
Lopez-Marino, S.
Saucedo, E.
JOURNAL OF PHYSICS D-APPLIED PHYSICS, 2016, 49 (08)
[4] Preparing Cu2ZnSnSe4 thin film solar cells based on selenium containing precursors
Li, Xiang
Wang, Shurong
Liao, Hua
Yang, Shuai
Li, Xinyu
Wang, Tingbao
Liu, Xin
Li, Qiulian
Li, Jingjin
OPTICAL MATERIALS, 2021, 111
[5] Refractive index extraction and thickness optimization of Cu2ZnSnSe4 thin film solar cells
ElAnzeery, Hossam
El Daif, Ounsi
Buffiere, Marie
Oueslati, Souhaib
Ben Messaoud, Khaled
Agten, Dries
Brammertz, Guy
Guindi, Rafik
Kniknie, Bas
Meuris, Marc
Poortmans, Jef
PHYSICA STATUS SOLIDI A-APPLICATIONS AND MATERIALS SCIENCE, 2015, 212 (09): : 1984 - 1990
[6] Single elementary target-sputtered Cu2ZnSnSe4 thin film solar cells
Jo, Yeon Hwa
Mohanty, Bhaskar Chandra
Yeon, Deuk Ho
Lee, Seung Min
Cho, Yong Soo
SOLAR ENERGY MATERIALS AND SOLAR CELLS, 2015, 132 : 136 - 141
[7] Revealing the beneficial effects of Ge doping on Cu2ZnSnSe4 thin film solar cells
Neuschitzer, Markus
Espindola Rodriguez, Moises
Guc, Maxim
Marquez, Jose A.
Giraldo, Sergio
Forbes, Ian
Perez-Rodriguez, Alejandro
Saucedo, Edgardo
JOURNAL OF MATERIALS CHEMISTRY A, 2018, 6 (25) : 11759 - 11772
[8] Influence of annealing condition on the photovoltaic performance of Cu2ZnSnSe4 thin film solar cells
Kuo, Shou-Yi
Yang, Jui-Fu
Lai, Fang-, I
Lin, Chun-Jung
2013 IEEE 39TH PHOTOVOLTAIC SPECIALISTS CONFERENCE (PVSC), 2013, : 353 - 355
[9] Effect of selenization on sprayed Cu2ZnSnSe4 thin film solar cell
Kim, SeongYeon
Kim, JunHo
THIN SOLID FILMS, 2013, 547 : 178 - 180
[10] Sulfurization of co-evaporated Cu2ZnSnSe4 thin film solar cells: The role of Na
de la Cueva, L.
Sanchez, Y.
Calvo-Barrio, L.
Oliva, F.
Izquierdo-Roca, V.
Khelifi, S.
Bertram, T.
Merino, J. M.
Leon, M.
Caballero, R.
SOLAR ENERGY MATERIALS AND SOLAR CELLS, 2018, 186 : 115 - 123

← 1 2 3 4 5 →