Vibration-rotation tunneling spectra of the water pentamer: Structure and dynamics

被引：286
|
作者：
Liu, K
Brown, MG
Cruzan, JD
Saykally, RJ
机构：
[1] Department of Chemistry, University of California, Berkeley
来源：
SCIENCE | 1996年 / 271卷 / 5245期
关键词：
D O I：
10.1126/science.271.5245.62
中图分类号：
O [数理科学和化学]; P [天文学、地球科学]; Q [生物科学]; N [自然科学总论];
学科分类号：
07 ; 0710 ; 09 ;
摘要：
Far-infrared laser vibration-rotation tunneling spectroscopy was used to measure an intermolecular vibration (81.19198 wave numbers) of the isolated water (D2O) pentamer, Relational analysis supports the chiral, slightly puckered ring structure predicted by theory, The experimentally deduced interoxygen separations for the water clusters up to the pentamer showed exponential convergence toward the corresponding distance in bulk phase water.
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页码：62 / 64
页数：3
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