Selective separation of germanium(IV) by iminodiacetic acid-type chitosan chelating resin

被引：10
|
作者：
Inukai, Y
Kaida, Y
Yasuda, S
机构：
[1] Materials Chemistry Department, Kyushu Natl. Indust. Res. Institute, AIST, Tosu, Saga 841, Shuku-machi
来源：
ANALYTICAL SCIENCES | 1997年 / 13卷 / 03期
关键词：
germanium; chitosan; iminodiacetic acid-type chelating resin; semimetal; polyamine-type chelating resin;
D O I：
10.2116/analsci.13.339
中图分类号：
O65 [分析化学];
学科分类号：
070302 ; 081704 ;
摘要：
An iminodiacetic acid-type chitosan chelating resin selectively adsorbed germanium(IV) from aqueous solutions over the range of strongly acidic to weakly basic media. The adsorption capacity of the chitosan resin for germanium(IV) was about 1 mmol g(-1) in acidic media. The selective separation of germanium(IV) from tellurium(VI) and boron was achieved with a column method using the chitosan resin. The breakthrough points of germanium(IV) in the chitosan resin columns were about 70 bed volumes over the range of strongly acidic to weakly basic media. The germanium(IV) adsorbed on the column was almost quantitatively recovered by elution with aqueous sodium hydroxide. On the other hand, it was difficult to separate germanium(IV) from tellurium(VI) using a column of the polyamine-type chitosan chelating resin.
引用
下载
收藏
页码：339 / 344
页数：6
相关论文
共 50 条
  • [31] Selective separation of mercury(II) using a synthetic resin containing amine and mercaptan as chelating groups
    Atia, AA
    Donia, AM
    Elwakeel, KZ
    REACTIVE & FUNCTIONAL POLYMERS, 2005, 65 (03): : 267 - 275
  • [32] Cobalt separation from waste mobile phone batteries using selective precipitation and chelating resin
    Sayed M. Badawy
    A. A. Nayl
    R. A. El Khashab
    M. A. El-Khateeb
    Journal of Material Cycles and Waste Management, 2014, 16 : 739 - 746
  • [33] Selective separation of Cr(III) and Fe(III) from liquid effluents using a chelating resin
    Fernandes, Sandra
    Romao, Ines S.
    Abreu, Carlos M. R.
    Quina, Margarida J.
    Gando-Ferreira, Licinio M.
    WATER SCIENCE AND TECHNOLOGY, 2012, 66 (09) : 1968 - 1976
  • [34] Cobalt separation from waste mobile phone batteries using selective precipitation and chelating resin
    Badawy, Sayed M.
    Nayl, A. A.
    El Khashab, R. A.
    El-Khateeb, M. A.
    JOURNAL OF MATERIAL CYCLES AND WASTE MANAGEMENT, 2014, 16 (04) : 739 - 746
  • [35] Preconcentration and separation of palladium(II) and platinum(IV) on a dithizone anchored poly(vinylpyridine)-based chelating resin
    Anal Chimica Acta, 2-3 (217):
  • [36] SEPARATION OF PLATINUM AND PALLADIUM USING A CHELATING RESIN CONTAINING QUINALDINIC ACID AMIDE GROUP
    KONAR, B
    BASU, S
    DAS, J
    INDIAN JOURNAL OF CHEMISTRY SECTION A-INORGANIC BIO-INORGANIC PHYSICAL THEORETICAL & ANALYTICAL CHEMISTRY, 1992, 31 (09): : 735 - 736
  • [37] Preconcentration and separation of palladium(II) and platinum(IV) on a dithizone anchored poly(vinylpyridine)-based chelating resin
    Shah, R
    Devi, S
    ANALYTICA CHIMICA ACTA, 1997, 341 (2-3) : 217 - 224
  • [38] CHROMATOGRAPHIC-SEPARATION BY A NEW CHELATING RESIN CONTAINING BETA-HYDROXYDITHIOCINNAMIC ACID
    LIH, JJ
    YEH, KY
    LIU, CY
    FRESENIUS JOURNAL OF ANALYTICAL CHEMISTRY, 1990, 336 (01): : 12 - 15
  • [39] Selective elution of nickel and cobalt from iminodiacetic acid cation exchange resin using ammoniacal solutions
    Littlejohn, Patrick
    Vaughan, James
    HYDROMETALLURGY, 2014, 141 : 24 - 30
  • [40] Catechol-Functionalized Chitosan Synthesis and Selective Extraction of Germanium (IV) from Acidic Solutions
    Patel, Madhav
    Karamalidis, Athanasios K.
    INDUSTRIAL & ENGINEERING CHEMISTRY RESEARCH, 2023, 62 (06) : 2892 - 2903
12345