C60- mean lifetime as a function of electron energy and molecular temperature

被引:16
|
作者
Vasil'ev, YV [1 ]
Abzalimov, RR
Nasibullaev, SK
Drewello, T
机构
[1] RAS, Ufa Res Ctr, Inst Phys Mol & Crystals, Ufa, Russia
[2] Bashkir State Agr Univ, Ufa, Russia
[3] Bashkir State Univ, Ufa 450074, Russia
[4] Univ Warwick, Coventry CV4 7AL, W Midlands, England
关键词
electron capture; electron autodetachment; negative ion; lifetime; fullerenes;
D O I
10.1081/FST-120027161
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
The electron autodetachment rate constant of the negative ion C-60(-) has been determined as a function of both electron energy and molecular temperature. The experimental findings provide proof of the statistical nature of the electron auto-emission from C-60(-). The experimental data have been rationalized within the framework of statistical transition state theory.
引用
收藏
页码:229 / 234
页数:6
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