Microwave-assisted anomeric deacetylation of ribofuranoses with Fe(III) reagents

被引：0

作者：

Wang, Qiang ^{[1
]}

Liu, Guodong ^{[2
]}

Gong, Shanshan ^{[1
]}

Sun, Qi ^{[1
]}

机构：

[1] Jiangxi Sci & Technol Normal Univ, Jiangxi Key Lab Organ Chem, 605 Fenglin Ave, Nanchang 330013, Jiangxi, Peoples R China

[2] Jiangxi Prov Coll & Univ, High Level Engn Res Ctr Biopharmaceut Mol & Diagn, Nanchang 330013, Jiangxi, Peoples R China

来源：

ADVANCED RESEARCH ON CIVIL ENGINEERING, MATERIALS ENGINEERING AND APPLIED TECHNOLOGY | 2014年 / 859卷

关键词：

ribofuranose; deacetylation; deprotection; microwave; FeCl3.6H(2)O;

D O I：

10.4028/www.scientific.net/AMR.859.337

中图分类号：

TP39 [计算机的应用];

学科分类号：

081203 ; 0835 ;

摘要：

Treatment of protected furanoses with FeCl3-6H(2)O in acetonitrile with microwave irradiation provides an efficient and mild protocol for regioselective removal of anomeric O-acetyl group. This method features cost efficient reagents, simple procedures, and high yields. The experimental results proved that microwave irradiation could notably shorten the reaction time and increase the product yield compared to the conventional thermal heating condition.

引用

页码：337 / +

页数：2

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