Surface oxygen complexes as governors of neopentane sorption in multiwalled carbon nanotubes

被引：17
|
作者：
Ötvös, Z
Onyestyák, G
Hancz, A
Kiricsi, I
Rees, LVC
机构：
[1] Hungarian Acad Sci, Chem Res Ctr, Inst Catalysis & Surface Chem, H-1525 Budapest, Hungary
[2] Univ Szeged, Dept Solid State & Radiochem, H-6701 Szeged, Hungary
[3] Univ Szeged, Appl & Environm Chem Dept, H-6720 Szeged, Hungary
[4] Univ Edinburgh, Sch Chem, Edinburgh EH9 3JJ, Midlothian, Scotland
来源：
CARBON | 2006年 / 44卷 / 09期
基金：
匈牙利科学研究基金会;
关键词：
carbon nanotubes; temperature programmed desorption; surface oxygen complexes; adsorption properties;
D O I：
10.1016/j.carbon.2006.01.005
中图分类号：
O64 [物理化学（理论化学）、化学物理学];
学科分类号：
070304 ; 081704 ;
摘要：
Multiwalled carbon nanotube (MWCNT) samples were obtained by purification and ball-milling of a MWCNT sample synthesized by catalytic chemical vapor decomposition. These samples were oxidized with KMnO4-H2SO4 solution. A heat treatment was employed to decompose the oxygenated groups created by the oxidation treatment. The samples were characterized by transmission electron microscopy (TEM), adsorption of nitrogen, pore size distribution, and by thermogravimetric analysis combined with mass spectroscopy (TG-MS). The dynamics of 2,2-dimethyl-propane (neopentane) sorption was studied by frequency-response (FR) spectroscopy. The FR spectra obtained clearly demonstrate the effect of (a) the ball-milling, (b) the oxidative treatment and (c) the heat treatment on the sorption uptake processes involved in these treated samples. (C) 2006 Elsevier Ltd. All rights reserved.
引用
收藏
页码：1665 / 1672
页数：8
相关论文
共 50 条
  • [41] Antilocalization in multiwalled carbon nanotubes
    Liu, K
    Roth, S
    Düsberg, GS
    Kim, GT
    Popa, D
    Mukhopadhyay, K
    Doome, R
    Nagy, JB
    PHYSICAL REVIEW B, 2000, 61 (03): : 2375 - 2379
  • [42] Phonons in multiwalled carbon nanotubes
    Popov, VN
    Henrard, L
    STRUCTURAL AND ELECTRONIC PROPERTIES OF MOLECULAR NANOSTRUCTURES, 2002, 633 : 425 - 428
  • [43] On the unzipping of multiwalled carbon nanotubes
    dos Santos, R. P. B.
    Perim, E.
    Autreto, P. A. S.
    Brunetto, Gustavo
    Galvao, D. S.
    NANOTECHNOLOGY, 2012, 23 (46)
  • [44] Evaluating the biological risk of functionalized multiwalled carbon nanotubes and functionalized oxygen-doped multiwalled carbon nanotubes as possible toxic, carcinogenic, and embryotoxic agents
    Lara-Martinez, Luis A.
    Masso, Felipe
    Gonzalez, Eduardo Palacios
    Garcia-Pelaez, Isabel
    Contreras-Ramos, Alejandra
    Valverde, Mahara
    Rojas, Emilio
    Cervantes-Sodi, Felipe
    Hernandez-Gutierrez, Salomon
    INTERNATIONAL JOURNAL OF NANOMEDICINE, 2017, 12 : 7695 - 7707
  • [45] Synthesis of multiwalled carbon nanotubes
    Jacques, D
    Villain, S
    Rao, AM
    Andrews, R
    Derbyshire, F
    Dickey, EC
    Qian, DL
    AMORPHOUS AND NANOSTRUCTURED CARBON, 2000, 593 : 15 - 20
  • [46] Insight into the modification of electrodonor properties of multiwalled carbon nanotubes via oxygen plasma: Surface functionalization versus amorphization
    Duch, J.
    Mazur, M.
    Golda-Cepa, M.
    Podobinski, J.
    Piskorz, W.
    Kotarba, A.
    CARBON, 2018, 137 : 425 - 432
  • [47] Surface covalent grafting of multiwalled carbon nanotubes with poly(ethylene terephthalate)
    Zheng, Hua
    Zhang, Chen
    Wang, Zhao-Xu
    Du, Zhong-Jie
    Li, Hang-Quan
    Gaofenzi Cailiao Kexue Yu Gongcheng/Polymeric Materials Science and Engineering, 2009, 25 (08): : 138 - 140
  • [48] Magnetic iron-containing nanoparticles on the surface of multiwalled carbon nanotubes
    Alexey V. Sobolev
    Serguei V. Savilov
    Nikolai B. Cherkasov
    Igor A. Presniakov
    Anton S. Ivanov
    Hyperfine Interactions, 2012, 207 : 29 - 32
  • [49] Growth of MoS2 layers on the surface of multiwalled carbon nanotubes
    V. O. Koroteev
    A. V. Okotrub
    Yu. V. Mironov
    O. G. Abrosimov
    Yu. V. Shubin
    L. G. Bulusheva
    Inorganic Materials, 2007, 43 : 236 - 239
  • [50] Influence of surface oxides on the adsorption of naphthalene onto multiwalled carbon nanotubes
    Cho, Hyun-Hee
    Smith, Billy A.
    Wnuk, Joshua D.
    Fairbrother, D. Howard
    Ball, William P.
    ENVIRONMENTAL SCIENCE & TECHNOLOGY, 2008, 42 (08) : 2899 - 2905
12345