Quantitative theory of surface tension and surface potential of aqueous solutions of electrolytes

被引：78
|
作者：
Markin, VS [1 ]
Volkov, AG
机构：
[1] UT SW Med Ctr, Dept Anesthesiol, Dallas, TX 75390 USA
[2] Oakwood Coll, Dept Chem, Huntsville, AL 35896 USA
来源：
JOURNAL OF PHYSICAL CHEMISTRY B | 2002年 / 106卷 / 45期
关键词：
D O I：
10.1021/jp026229d
中图分类号：
O64 [物理化学（理论化学）、化学物理学];
学科分类号：
070304 ; 081704 ;
摘要：
The surface tension and surface potential of aqueous solutions of inorganic electrolytes are calculated. The new model includes image forces at liquid interfaces, ions of finite radii, the hydrophobic effect, and the Parsons-Zobel effect. For the first time, a good correlation between theory and experimental data both qualitatively and quantitatively is obtained for different inorganic salts over a wide range of concentrations.
引用
收藏
页码：11810 / 11817
页数：8
相关论文
共 50 条
  • [21] The surface tension of aqueous solutions of paratoluidine
    Gans, DM
    Harkins, WD
    JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1930, 52 : 2289 - 2295
  • [22] Surface tension of aqueous binary solutions
    Yamada, M
    Fukusako, S
    Kawanami, T
    Sawada, I
    Horibe, A
    INTERNATIONAL JOURNAL OF THERMOPHYSICS, 1997, 18 (06) : 1483 - 1493
  • [23] SURFACE TENSION OF CHLOROHYDRIN AQUEOUS SOLUTIONS
    MYSZKOWS.J
    ZIELINSK.AZ
    MILCHERT, E
    PTASZYNS.S
    ROCZNIKI CHEMII, 1970, 44 (06): : 1283 - &
  • [24] SURFACE TENSION OF AQUEOUS SOLUTIONS OF AMMONIA
    EFREMOV, YV
    GOLUBEV, IF
    ZHURNAL FIZICHESKOI KHIMII, 1962, 36 (05): : 999 - 1000
  • [25] Surface tension of aqueous binary solutions
    M. Yamada
    S. Fukusako
    T. Kawanami
    I. Sawada
    A. Horibe
    International Journal of Thermophysics, 1997, 18 (6) : 1483 - 1493
  • [26] SURFACE-POTENTIAL AND SURFACE-TENSION OF AQUEOUS 2-HALOGENOETHANOL-ETHANOL SOLUTIONS
    PALUCH, M
    KOT, M
    COLLOID AND POLYMER SCIENCE, 1993, 271 (05) : 507 - 511
  • [27] ELECTRIC SURFACE POTENTIAL + SURFACE TENSION OF AQUEOUS SOLUTIONS OF SOME HALOGENO-DERIVATIVES OF QUINOLINE
    KAMIENSKI, B
    PALUCH, M
    WALIGORA, B
    BULLETIN DE L ACADEMIE POLONAISE DES SCIENCES-SERIE DES SCIENCES CHIMIQUES, 1964, 12 (02): : 117 - &
  • [28] ELECTRIC SURFACE POTENTIAL AND SURFACE TENSION OF AQUEOUS SOLUTIONS OF ALPHA- AND BETA-BENZALDOXIMES
    KAMIENSKI, B
    KRAUSS, E
    BULLETIN DE L ACADEMIE POLONAISE DES SCIENCES-SERIE DES SCIENCES CHIMIQUES, 1966, 14 (02): : 149 - +
  • [29] LIMITING LAWS FOR SURFACE TENSION OF SOLUTIONS OF STRONG ELECTROLYTES
    BRAVINA, VE
    SOVIET PHYSICS JETP-USSR, 1958, 6 (04): : 822 - 823
  • [30] Effect of electrolytes on surface tension of ionic surfactant solutions
    Para, G
    Jarek, E
    Warszynski, P
    Adamczyk, Z
    COLLOIDS AND SURFACES A-PHYSICOCHEMICAL AND ENGINEERING ASPECTS, 2003, 222 (1-3) : 213 - 222
12345