Crystal structure of the low-temperature form of K3PO4

被引：22
|
作者：
Voronin, V. I.
Ponosov, Yu. S.
Berger, I. F.
Proskurnina, N. V.
Zubkov, V. G.
Tyutyunnik, A. P.
Bushmelev, S. N.
Balagurov, A. M.
Sheptyakov, D. V.
Burmakin, E. I.
Shekhtman, G. Sh.
Vovkotrub, E. G.
机构：
[1] Russian Acad Sci, Inst Met Phys, Ural Div, Ekaterinburg 620219, Russia
[2] Russian Acad Sci, Inst Solid State Chem, Ural Div, Ekaterinburg 620219, Russia
[3] Joint Inst Nucl Res, Dubna 141980, Russia
[4] ETH, Neutron Scattering Lab, CH-5232 Villigen, Switzerland
[5] Paul Scherrer Inst, CH-5232 Villigen, Switzerland
[6] Russian Acad Sci, Ural Div, Inst High Temp Electrochem, Ekaterinburg 620219, Russia
来源：
INORGANIC MATERIALS | 2006年 / 42卷 / 08期
关键词：
D O I：
10.1134/S0020168506080206
中图分类号：
T [工业技术];
学科分类号：
08 ;
摘要：
The crystal structure of the low-temperature form of K3PO4 has been determined for the first time using neutron diffraction (Rietveld method) and Raman spectroscopy: orthorhombic cell (sp. gr. Pnma, Z=4), lattice parameters a = 1.12377(2) nm, b = 0.81046(1) nm, c = 0.59227(1) nm. The structure is made up of isolated [PO4] tetrahedra, with the potassium ions in between.
引用
收藏
页码：908 / 913
页数：6
相关论文
共 50 条
  • [41] Orthorhombic K3V3(PO4)4: A low-temperature cathode material for potassium-ion batteries
    Luo, Rui-Jie
    Du, Chong-Yu
    Ma, Cui
    Zeng, Jie
    Xu, Xuan
    Qian, Zhe
    Mei, Zhe
    Zhou, Zi-Ting
    Zhu, Ze-Yu
    Zhou, Yong-Ning
    CHEMICAL ENGINEERING JOURNAL, 2024, 491
  • [42] Synthesis of HTLcs modified by K3PO4 for side chain alkylation of toluene with methanol
    Hao, Chunyao
    Wen, Yueli
    Wang, Bin
    Ahmad, Faraz
    Liu, Yuhua
    Li, Huijun
    Huang, Wei
    GREEN ENERGY & ENVIRONMENT, 2021, 6 (06) : 961 - 967
  • [43] Structural study of the low-temperature phase of TlH2PO4 at 180 K
    Alvarez-Otero, E
    Madariaga, G
    Peral, I
    Folcia, CL
    Ríos, S
    ACTA CRYSTALLOGRAPHICA SECTION B-STRUCTURAL SCIENCE, 2002, 58 : 750 - 759
  • [44] Mechanochemical solid state synthesis of copper(I)/NHC complexes with K3PO4
    Remy-Speckmann, Ina
    Zimmermann, Birte M.
    Gorai, Mahadeb
    Lerch, Martin
    Teichert, Johannes F.
    BEILSTEIN JOURNAL OF ORGANIC CHEMISTRY, 2023, 19 : 440 - 447
  • [45] LOW-TEMPERATURE CRYSTAL-STRUCTURE OF CE3AL
    LAWSON, AC
    LAWRENCE, JM
    THOMPSON, JD
    WILLIAMS, A
    PHYSICA B, 1990, 163 (1-3): : 587 - 590
  • [46] Biodiesel production from soybean oil transesterification in subcritical methanol with K3PO4 as a catalyst
    Yin, Jian-Zhong
    Ma, Zhen
    Shang, Zi-Yang
    Hu, Da-Peng
    Xiu, Zhi-Long
    FUEL, 2012, 93 (01) : 284 - 287
  • [47] ON LOW-TEMPERATURE K3NO3
    JANSEN, M
    WOLF, B
    ZEITSCHRIFT FUR ANORGANISCHE UND ALLGEMEINE CHEMIE, 1983, 502 (07): : 153 - 157
  • [48] LOW-TEMPERATURE CRYSTAL-STRUCTURE OF TBASO4 AND DYASO4
    LONG, FG
    STAGER, CV
    CANADIAN JOURNAL OF PHYSICS, 1977, 55 (18) : 1633 - 1640
  • [49] Water Activities and Equilibrium Phase Behavior for the Binary K3PO4(aq), K2SO4(aq) and the Ternary K3PO4 + K2SO4 + H2O Systems at Various Temperatures from 298.15 to 353.15 K
    Sidi Mohammed Aboufaris El Alaoui
    Mohamed EL Guendouzi
    Journal of Solution Chemistry, 2018, 47 : 47 - 64
  • [50] POLYMORPHISM OF PARA CHLOROPHENOL .2. CRYSTAL-STRUCTURE AT LOW-TEMPERATURE OF METASTABLE FORM (BETA FORM)
    PERRIN, M
    MICHEL, P
    ACTA CRYSTALLOGRAPHICA SECTION B-STRUCTURAL SCIENCE, 1973, B 29 (FEB15): : 258 - 263
12345