On participation of hydroxide ions in the anodic dissolution of metals in aqueous electrolyte solutions

被引：6
|
作者：
Byk, MV [1 ]
Tkalenko, DA [1 ]
Tkalenko, MD [1 ]
机构：
[1] Natl Tech Univ Ukraine, KPI, UA-03056 Kiev, Ukraine
来源：
PROTECTION OF METALS | 2004年 / 40卷 / 03期
关键词：
Hydroxide; Inorganic Chemistry; Catalytic Property; Electrolyte Solution; Reaction Order;
D O I：
10.1023/B:PROM.0000028926.39111.7b
中图分类号：
TF [冶金工业];
学科分类号：
0806 ;
摘要：
The increase in the anodic current at a fixed potential is formally explained by taking into account the shift of anodic partial curves with a change in pH, without invoking any concept of catalytic properties of hydroxide ions and their effect on the kinetics of any stage of the anodic process. By using the suggested thermodynamic approach, the experimental reaction orders of the anodic process in hydroxide ions are quantitatively explained.
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页码：294 / 296
页数：3
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