On participation of hydroxide ions in the anodic dissolution of metals in aqueous electrolyte solutions

被引：6
|
作者：
Byk, MV [1 ]
Tkalenko, DA [1 ]
Tkalenko, MD [1 ]
机构：
[1] Natl Tech Univ Ukraine, KPI, UA-03056 Kiev, Ukraine
来源：
PROTECTION OF METALS | 2004年 / 40卷 / 03期
关键词：
Hydroxide; Inorganic Chemistry; Catalytic Property; Electrolyte Solution; Reaction Order;
D O I：
10.1023/B:PROM.0000028926.39111.7b
中图分类号：
TF [冶金工业];
学科分类号：
0806 ;
摘要：
The increase in the anodic current at a fixed potential is formally explained by taking into account the shift of anodic partial curves with a change in pH, without invoking any concept of catalytic properties of hydroxide ions and their effect on the kinetics of any stage of the anodic process. By using the suggested thermodynamic approach, the experimental reaction orders of the anodic process in hydroxide ions are quantitatively explained.
引用
收藏
页码：294 / 296
页数：3
相关论文
共 50 条
  • [1] On Participation of Hydroxide Ions in the Anodic Dissolution of Metals in Aqueous Electrolyte Solutions
    M. V. Byk
    D. A. Tkalenko
    M. D. Tkalenko
    Protection of Metals, 2004, 40 : 294 - 296
  • [2] ANODIC-DISSOLUTION OF METALS .2. ANODIC-DISSOLUTION OF INDIUM IN AQUEOUS PERCHLORATE SOLUTIONS
    SZALMA, J
    FARKAS, J
    KISS, L
    JOO, P
    ACTA CHIMICA ACADEMIAE SCIENTARIUM HUNGARICAE, 1981, 108 (04): : 413 - 423
  • [3] HIGH-RATE ANODIC-DISSOLUTION OF METALS IN NONAQUEOUS AND AQUEOUS-ORGANIC ELECTROLYTE-SOLUTIONS
    LILIN, SA
    RUSSIAN JOURNAL OF ELECTROCHEMISTRY, 1994, 30 (04) : 521 - 532
  • [4] ANODIC-DISSOLUTION OF METALS .3. MECHANISM OF THE ANODIC-DISSOLUTION OF INDIUM IN AQUEOUS PERCHLORATE SOLUTIONS
    SZALMA, J
    FARKAS, J
    KISS, L
    JOO, P
    SZABO, M
    MAGYAR KEMIAI FOLYOIRAT, 1983, 89 (08): : 353 - 358
  • [5] ANODIC SOLUTION OF METALS .2. ANODIC-DISSOLUTION OF INDIUM IN AQUEOUS PERCHLORATE SOLUTIONS
    SZALMA, J
    FARKAS, J
    KISS, L
    JOO, P
    MAGYAR KEMIAI FOLYOIRAT, 1981, 87 (12): : 543 - 547
  • [6] ANODIC DISSOLUTION OF PB IN AQUEOUS SOLUTIONS
    JOHNSON, JW
    WU, CK
    JAMES, WJ
    CORROSION SCIENCE, 1968, 8 (05) : 309 - &
  • [7] MECHANISM OF ANODIC DISSOLUTION OF TIN IN SODIUM HYDROXIDE SOLUTIONS
    AWAD, SA
    KASSAB, A
    JOURNAL OF ELECTROANALYTICAL CHEMISTRY, 1970, 26 (01): : 127 - &
  • [8] ANODIC-DISSOLUTION OF GOLD IN ALKALINE CYANIDE SOLUTIONS .3. INFLUENCE OF HYDROXIDE IONS
    BECK, RY
    KOSOLAPOV, GV
    SIBIRSKII KHIMICHESKII ZHURNAL, 1991, (03): : 40 - 46
  • [9] ANODIC DISSOLUTION OF ZN IN AQUEOUS SALT SOLUTIONS
    JOHNSON, JW
    SUN, YC
    JAMES, WJ
    CORROSION SCIENCE, 1971, 11 (03) : 153 - &
  • [10] ANODIC-DISSOLUTION OF COPPER IN THE PRESENCE OF F- IONS IN AQUEOUS ACIDIC SOLUTIONS
    POTVIN, E
    DROGOWSKA, M
    MENARD, H
    BROSSARD, L
    CANADIAN JOURNAL OF CHEMISTRY-REVUE CANADIENNE DE CHIMIE, 1987, 65 (09): : 2109 - 2113
12345