Recent advances in the coordination chemistry of cerium(IV) complexes

被引：82

作者：

So, Yat-Ming ^{[1
]}

Leung, Wa-Hung ^{[1
]}

机构：

[1] Hong Kong Univ Sci & Technol, Dept Chem, Kowloon, Hong Kong, Peoples R China

来源：

COORDINATION CHEMISTRY REVIEWS | 2017年 / 340卷

关键词：

Cerium; Tetravalent complexes; O-donor ligands; CATALYZED WATER OXIDATION; CHEMICAL-VAPOR-DEPOSITION; ACTINIDES ANNUAL SURVEY; CERIC AMMONIUM-NITRATE; KLAUI TRIPODAL LIGAND; TETRAVALENT CERIUM; ORGANOMETALLIC CHEMISTRY; CRYSTAL-STRUCTURE; IMIDO COMPLEX; CE-IV;

D O I：

10.1016/j.ccr.2016.12.009

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Despite widespread applications of tetravalent cerium compounds in organic synthesis and catalysis, the coordination and organometallic chemistry of cerium(IV) complexes has not been well explored, due, in part, to the high oxidizing power of Ce(IV). Using chelating O-donor supporting ligands, stable tetravalent cerium complexes bearing various ligand functionalities have been isolated, thus making it possible to investigate the reaction chemistry of cerium(IV) complexes systematically. This review summarizes the recent developments of the coordination chemistry of cerium(IV) complexes bearing O-, N-, and C-donor ligands. Special attention will be directed to cerium(IV) complexes supported by a tripodal oxygen ligand. (C) 2016 Elsevier B.V. All rights reserved.

引用

页码：172 / 197

页数：26

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