Systematic Method for the Incorporation of the {(η6-Arene)Fe} Fragment into Carborane Cages via [(η6-Arene)Fe]2+ Dications. A Series of [3-(η6-Arene)-closo-3,1,2-FeC2B9H11] Complexes. Reliable Synthesis of Polymethylated [(η6-Arene)2Fe]2+ Cations

被引：9

作者：

Stibr, B. ^{[1
]}

Bakardjiev, M. ^{[1
]}

Holub, Josef ^{[1
]}

Ruzicka, Ales ^{[2
]}

Kvicalova, Magdalena ^{[1
]}

机构：

[1] Acad Sci Czech Republic, Inst Inorgan Chem, CZ-25068 Rez, Czech Republic

[2] Univ Pardubice, Fac Chem Technol, Dept Gen & Inorgan Chem, Pardubice 53210, Czech Republic

来源：

INORGANIC CHEMISTRY | 2009年 / 48卷 / 23期

关键词：

ORGANOTRANSITION-METAL METALLACARBORANES; MAGNETIC-RESONANCE SPECTROSCOPY; IRON COMPLEXES; NUCLEOPHILIC-ADDITION; HYDROCARBONS; RUTHENIUM; BENZENE; LIGANDS; COBALT;

D O I：

10.1021/ic901982q

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Developed was a systematic method for the incorporation of the {(eta(6)-arene)Fe} fragment into a carborane cage. Reactions between [(eta(6)-arene)(2)Fe](PF6)(2) salts and Tl-2[nido-7,8-C2B9H11] in refluxing (CH2)(2)Cl-2 generated a series of [3-(eta(6)-arene)-closo-3,1,2-FeC2B9H11] neutral complexes with variable types of polymethylated arene ligands in the structure. The structures of durene and hexamethylbenzene complexes were established by X-ray diffraction analyses. The work also shows that the original hi temperature method for the preparation of the [(eta(6)-arene)(2)Fe](2+) dications fails for mesitylene and durene compounds, which was overcome by a reliable room-temperature modification.

引用

页码：10904 / 10906

页数：3

共 29 条

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INORGANIC CHEMISTRY, 2011, 50 (07) : 3097 - 3102
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SNEDDON, LG
ORGANOMETALLICS, 1983, 2 (05) : 674 - 678
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INORGANIC CHEMISTRY, 1984, 23 (24) : 3992 - 3999
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Kerimkulova, Aygul
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INORGANICA CHIMICA ACTA, 2019, 492 : 108 - 118
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ORGANOMETALLICS, 1984, 3 (09) : 1396 - 1402
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TYURIN, VD
NEKHAEV, AI
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KONDRATEVA, MG
BATSANOV, AS
STRUCHKOV, YT
JOURNAL OF ORGANOMETALLIC CHEMISTRY, 1983, 243 (03) : 323 - 330

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