Unexpected reduction pathway of a Co2+ salt to [HCo(CO)4] via [Co2(CO)8] in an ionic liquid

被引：8

作者：

Hebrard, Frederic

Kalck, Philippe

Saussine, Lucien

Magna, Lionel

Olivier-Bourbigou, Helene

机构：

[1] Ecole Natl Super Ingn Arts Chim & Technol, Lab Catalyse Chim Fine & Polymeres, F-31077 Toulouse 4, France

[2] Inst Francais Petr, F-69390 Vernaison, France

来源：

DALTON TRANSACTIONS | 2007年 / 02期

关键词：

Cobalt compounds;

D O I：

10.1039/b616169n

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

In the 1-butyl-3-methylimidazolium bis(trifluoromethyl-sulfonyl)amide ionic liquid ([BMI][NTf2]), [Co(NTf2)(2)] is reduced under 5.5 MPa of H-2-CO to [Co-2(CO)(8)] prior to [HCo(CO)(4)], provided a pyridine ligand is present in the medium.

引用

页码：190 / 191

页数：2

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