Synthesis, Crystal Structure, and Magnetic and Water-induced Reversible Transformation Properties of {[Ni(IBG)(μ-H2O)(H2O)2]•2H2O}n

被引：0
|
作者：
Xu Han [1 ]
Liu Bin [2 ]
Pan Zhao-Rui [3 ]
机构：
[1] Huangshan Univ, Dept Chem & Chem Engn, Huangshan 245041, Peoples R China
[2] NW Univ Xian, Coll Chem, Key Lab Synthet & Nat Funct Mol Chem, Xian 710069, Peoples R China
[3] Nanjing Xiaozhuang Univ, Biochem & Environm Engn Coll, Nanjing 211171, Jiangsu, Peoples R China
来源：
CHINESE JOURNAL OF STRUCTURAL CHEMISTRY | 2014年 / 33卷 / 01期
关键词：
nickel complex; crystal structure; hydrogen bonds; COORDINATION POLYMER;
D O I：
暂无
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
A novel Ni-II complex {[Ni(IBG)(mu-H2O)(H2O)(2)]center dot 2H(2)O}(n) 1 (H(2)IBG = isophthaloylbisglycine) has been synthesized and characterized by single-crystal X-ray diffraction, elemental analysis, IR spectra, and thermogravimetric analysis. It crystallizes in monoclinic, space group P2/c with a = 15.40(2), b = 6.960(10), c = 7.865(11) angstrom, beta = 90.32(3)degrees, V = 843(2) angstrom(3), Z = 2, C12H18NiN2O11 M-r = 424.99, D-c = 1.675 g/cm(3), F(000) = 440, mu(MoK alpha) = 1.214 mm(-1), the final R = 0.0514 and wR = 0.1247 for 1078 observed reflections with I > 2 sigma(I). In the structure, each Ni-II center is situated in the center of a rather regular octahedron. Moreover, thermal stability has been studied and magnetic measurements show antiferromagnetic interactions for this complex.
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页码：27 / 32
页数：6
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