Intramolecular sulfur-assisted NaBH4 reduction of esters synthesis of 5-oxo-ETE and 5-oxo-12-HETE

被引：9

作者：

Khanapure, SP

Saha, G

Sivendran, S

Powell, WS

Rokach, J

机构：

[1] Florida Inst Technol, Claude Pepper Inst, Melbourne, FL 32901 USA

[2] Florida Inst Technol, Dept Chem, Melbourne, FL 32901 USA

[3] McGill Univ, Meakins Christie Labs, Montreal, PQ H2X 2P2, Canada

[4] McGill Univ, Dept Med, Montreal, PQ H2X 2P2, Canada

来源：

TETRAHEDRON LETTERS | 2000年 / 41卷 / 30期

基金：

英国医学研究理事会; 美国国家卫生研究院; 美国国家科学基金会;

关键词：

NaBH4; MeOH; 5-oxo-ETE;

D O I：

10.1016/S0040-4039(00)00943-6

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

Ester groups are reduced very efficiently in sulfur-containing molecules situated at close proximity to the ester group. We have used this procedure to regioselectively, efficiently and in high yield reduce an ester group in the presence of another ester group further removed from the sulfur atom. (C) 2000 Elsevier Science Ltd. All rights reserved.

引用

页码：5653 / 5657

页数：5

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