Synthesis and Resolution of Optically Active Topologically Chiral Catenane

被引：3

作者：

Ishizu, Yuki ^{[1
]}

Takeyoshi, Ayaka ^{[1
]}

Hasegawa, Eietsu ^{[1
]}

Iwamoto, Hajime ^{[1
]}

机构：

[1] Niigata Univ, Grad Sch Sci & Technol, Dept Chem, Nishi Ku, 8050 Ikarashi 2 No Cho, Niigata 9502181, Japan

来源：

CHEMISTRY LETTERS | 2020年 / 49卷 / 12期

基金：

日本学术振兴会;

关键词：

Catenane; Topological chirality; Chiral auxiliary; METATHESIS CATALYSTS; MOLECULAR MACHINES;

D O I：

10.1246/cl.200555

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

A topologically chiral [2]catenane was synthesized and resolved by a diastereomer method. The [2]catenane consisting of a C-s symmetrical crown ether and a C-s symmetrical ammonium macrocycle was obtained as a racemic mixture. Introduction of a chiral auxiliary to the [2]catenane gave a diastereomeric mixture which was successfully resolved. Removal of the chiral auxiliary from both enantiomers of the [2]catenane gave rise to minor images of their CD spectra.

引用

页码：1435 / 1438

页数：4

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