Electrochemical properties of solid electrolytes based on BaSm2S4

被引：3
|
作者：
Ushakova, Yu. N.
Kalinina, L. A. [1 ]
Yurlov, I. S. [1 ]
Bayderina, T. V. [1 ]
Murin, I. V. [2 ]
机构：
[1] Vyatka State Univ, State Educ Inst Higher Profess Training, Kirov, Russia
[2] St Petersburg State Univ, State Educ Inst Higher Profess Training, St Petersburg, Russia
来源：
RUSSIAN JOURNAL OF ELECTROCHEMISTRY | 2009年 / 45卷 / 06期
基金：
俄罗斯基础研究基金会;
关键词：
stoichiometric substances; barium thiosamarate; solid electrolytes; ionic and electronic transport numbers; ionic conductivity;
D O I：
10.1134/S1023193509060093
中图分类号：
O646 [电化学、电解、磁化学];
学科分类号：
081704 ;
摘要：
Solid solutions based on BaSm2S4 - x mol % BaS (Sm2S3) are obtained. Oxide intermediates were homogenized using chemical and mechanical mixing methods. The solid solution region is determined. Complex conductivity is studied and conductivity activation energy is calculated for samples with different history. Electrolytic properties of phases based on barium thiosamarate are studied. Vacancy mechanism of defect formation is suggested.
引用
收藏
页码：677 / 683
页数：7
相关论文
共 50 条
  • [21] SOLID POLYMER ELECTROLYTES WITH STABLE ELECTROCHEMICAL PROPERTIES.
    Carre, Claudine
    Hamaide, Thierry
    Guyot, Alain
    Mai, Christian
    British Polymer Journal, 1988, 20 (03): : 269 - 274
  • [22] Dual Doping: An Effective Method to Enhance the Electrochemical Properties of Li10GeP2S12-Based Solid Electrolytes
    Yang, Kun
    Dong, Jianying
    Zhang, Long
    Li, Yueming
    Wang, Limin
    JOURNAL OF THE AMERICAN CERAMIC SOCIETY, 2015, 98 (12) : 3831 - 3835
  • [23] Electrochemical Properties of Li10GeP2S12 Solid Electrolytes Synthesized Using a Solution-Based Method
    Hikima, Kazuhiro
    Kishi, Ryota
    Tsukasaki, Hirofumi
    Mori, Shigeo
    Muto, Hiroyuki
    Matsuda, Atsunori
    ACS APPLIED ENERGY MATERIALS, 2024, : 8788 - 8796
  • [24] ELECTROCHEMICAL REACTIONS IN SOLID ELECTROLYTES BASED ON ZRO2 AT HIGH TEMPERATURES
    GOKHSHTEIN, YP
    KHAIKIN, RA
    HIGH TEMPERATURE, 1969, 7 (05) : 965 - +
  • [25] Electrochemical SOx (x=2 or 3) gas sensor based on solid electrolytes
    Meng, GY
    Yang, PH
    Peng, DK
    SOLID-STATE IONIC DEVICES, 1999, 99 (13): : 324 - 334
  • [26] Synthesis of Complex Sulfide Phases BaSm2S4-Tm2S3 and Studies of Their Electrolytic Properties
    Mikhailichenko, T. V.
    Kalinina, L. A.
    Ushakova, Yu N.
    Shirokova, G. I.
    Tokareva, T. V.
    RUSSIAN JOURNAL OF ELECTROCHEMISTRY, 2011, 47 (05) : 556 - 562
  • [27] Synthesis of complex sulfide phases BaSm2S4-Tm2S3 and studies of their electrolytic properties
    T. V. Mikhailichenko
    L. A. Kalinina
    Yu. N. Ushakova
    G. I. Shirokova
    T. V. Tokareva
    Russian Journal of Electrochemistry, 2011, 47 : 556 - 562
  • [28] Electrochemical hydrogen isotope sensor based on solid electrolytes
    Matsumoto, H
    Hayashi, H
    Iwahara, H
    JOURNAL OF NUCLEAR SCIENCE AND TECHNOLOGY, 2002, 39 (04) : 367 - 370
  • [29] Preparation and electrochemical properties of nonwoven reinforced solid polymer electrolytes
    Heejung Kim
    Bookeun Oh
    Youngku Kang
    Polymer Bulletin, 2000, 44 : 509 - 515
  • [30] Preparation and electrochemical properties of nonwoven reinforced solid polymer electrolytes
    Kim, H
    Oh, B
    Kang, Y
    POLYMER BULLETIN, 2000, 44 (5-6) : 509 - 515
12345