Fast catalytic degradation of organic dye with air and MoO3:Ce nanofibers under room condition

被引:111
|
作者
Li, Wei [1 ]
Zhao, Shun [1 ]
Qi, Bin [1 ]
Du, Yang [1 ]
Wang, Xiaohong [1 ]
Huo, Mingxin [2 ]
机构
[1] NE Normal Univ, Key Lab Polyoxometalate Sci, Minist Educ, Fac Chem, Changchun 130024, Peoples R China
[2] NE Normal Univ, Sch Urban & Environm Sci, Changchun 130024, Peoples R China
基金
中国国家自然科学基金;
关键词
Catalytic wet air oxidation; Molybdenum oxide; Cerium oxide; Degradation of dye; Nanofibers; WET OXIDATION; VISIBLE-LIGHT; AZO-DYE; OXIDE; POLLUTANTS; REDUCTION; MECHANISM; CERIA; ACID;
D O I
10.1016/j.apcatb.2009.08.012
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
One-dimensional Ce doped MoO3 nanofibers with different Ce doping amount have been synthesized by a combination method of sol-gel process and electrospinning technique. X-ray diffraction (XRD), X-ray photoelectron spectrum (XPS), Fourier transform infrared spectroscopy (FT-IR), scanning electron microscopy (SEM) were used to characterize the resulting samples. These fibers are interesting for a number of catalytic applications. The best catalytic activity was obtained over 11.86 wt.% CeO2-doped MoO3 with 98% degradation effect of 0.3 g L-1 Safranin-T by air under room condition towards complete degradation products such as HCO3- and NO3- within 20 min. The leaching test showed that this MoO3:Ce nanofiber catalyst has an excellent stability and can be used as a rapid heterogeneous catalyst for about ten times by simply treatment. (C) 2009 Elsevier B.V. All rights reserved.
引用
收藏
页码:333 / 340
页数:8
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