BaTiO3-CoFe2O4-BaTiO3 trilayer composite thin films prepared by chemical solution deposition

Multiferroic BaTiO3-CoFe2O4-BaTiO3 thin films were synthesized by spin coating of Co(NO3)(2)-Fe(NO3)(3) and Ba(OAc)(2)-Ti(i-OPr)(4) dissolved in a mixture of acetic acid and dimethylformamide. Stepwise thermal treatment at 200, 400 and 800 degrees C led to the desired phases. The phase formation process was monitored by thermoanalytic, XRD, IR and Raman measurements. SEM was used to characterize the structure and thickness of each layer. Two samples with different thicknesses of perovskite and spinel layers are discussed. Sample 1 consists of 120 nm CoFe2O4 between two 70 nmBaTiO(3) layers. For sample 2, the 90nm BaTiO3 top and bottom layers are enclosing 220 nm CoFe2O4. The surface qualities were determined by AFM indicating rms roughness values of about 4nm. Magnetic investigations reveal slightly anisotropic behavior. Polarization measurements show hysteresis loops (P-S(max) =29 mu C cm(-2); P-R(max) = 17 mu C cm(-2)) with switching peaks at the corresponding coercive fields. (C) 2015 Elsevier Ltd. All rights reserved.