Changes in the thermophysical properties of microcrystalline cellulose as function of carbonization temperature

被引：51
|
作者：
Rhim, Yo-Rhin [2 ]
Zhang, Dajie [1 ]
Rooney, Michael [3 ]
Nagle, Dennis C. [1 ]
Fairbrother, D. Howard [4 ]
Herman, Cila [2 ]
Drewry, David G., III [1 ]
机构：
[1] Johns Hopkins Univ, Adv Technol Lab, Baltimore, MD 21211 USA
[2] Johns Hopkins Univ, Dept Mech Engn, Baltimore, MD 21218 USA
[3] Johns Hopkins Univ, Appl Phys Lab, Laurel, MD 20723 USA
[4] Johns Hopkins Univ, Dept Chem, Baltimore, MD 21218 USA
来源：
CARBON | 2010年 / 48卷 / 01期
关键词：
ORDERED POROUS CARBON; THERMAL-CONDUCTIVITY; CARBON/CARBON MATERIALS; PYROLYTIC-GRAPHITE; HEAT-CAPACITY; WOOD; DIFFUSIVITY; SPECTROSCOPY; DIFFRACTION; HYDROGEN;
D O I：
10.1016/j.carbon.2009.07.048
中图分类号：
O64 [物理化学（理论化学）、化学物理学];
学科分类号：
070304 ; 081704 ;
摘要：
Thermophysical properties of carbon materials derived from microcrystalline cellulose have been studied under vacuum and compared with earlier measurements conducted under nitrogen to better understand the influence of porosity, composition, microstructure, and atmosphere effects. The effective thermal conductivity in vacuum is lower than that observed in nitrogen primarily due to the conductivity of nitrogen gas. Radiation effects in both atmospheres were determined to be negligible. Reduction of thermal diffusivity in nitrogen was attributed to the effects of nitrogen gas phonon scattering. The trends for electrical and thermal property changes with structure are similar but not identical due to the differences in electron and phonon transport mechanisms. (C) 2009 Elsevier Ltd. All rights reserved.
引用
下载
收藏
页码：31 / 40
页数：10
相关论文
共 50 条
  • [31] Changes in Submicrometer Structure of Enzymatically Hydrolyzed Microcrystalline Cellulose
    Penttila, Paavo A.
    Varnai, Aniko
    Leppanen, Kirsi
    Peura, Marko
    Kallonen, Aki
    Jaaskelainen, Pentti
    Lucenius, Jessica
    Ruokolainen, Janne
    Siika-aho, Matti
    Viikari, Liisa
    Serimaa, Ritva
    BIOMACROMOLECULES, 2010, 11 (04) : 1111 - 1117
  • [32] Structural Changes in Microcrystalline Cellulose in Subcritical Water Treatment
    Tolonen, Lasse K.
    Zuckerstatter, Gerhard
    Penttila, Paavo A.
    Milacher, Walter
    Habicht, Wilhelm
    Serimaa, Ritva
    Kruse, Andrea
    Sixta, Herbert
    BIOMACROMOLECULES, 2011, 12 (07) : 2544 - 2551
  • [33] Characterisation of the interactive properties of microcrystalline cellulose-carboxymethyl cellulose hydrogels
    Zhao, G. H.
    Kapur, N.
    Carlin, B.
    Selinger, E.
    Guthrie, J. T.
    INTERNATIONAL JOURNAL OF PHARMACEUTICS, 2011, 415 (1-2) : 95 - 101
  • [34] Simultaneous carbonization and sulfonation of microcrystalline cellulose to obtain solid acid catalyst and carbon quantum dots
    Souza, M. C. G.
    Batista, A. C. F.
    Cuevas, R. F.
    da Silva Filho, W. J. F.
    Balanta, M. A. G.
    Champi, A.
    de Assuncao, R. M. N.
    BIORESOURCE TECHNOLOGY REPORTS, 2022, 19
  • [35] Thermophysical and mechanical properties of biological tissues as a function of temperature: a systematic literature review
    Bianchi, Leonardo
    Cavarzan, Fabiana
    Ciampitti, Lucia
    Cremonesi, Matteo
    Grilli, Francesca
    Saccomandi, Paola
    INTERNATIONAL JOURNAL OF HYPERTHERMIA, 2022, 39 (01) : 297 - 340
  • [36] Impact of degree of oxidation on the physicochemical properties of microcrystalline cellulose
    Hao, Jie
    Xu, Shuyi
    Xu, Naiyu
    Li, Duxin
    Linhardt, Robert J.
    Zhang, Zhenqing
    CARBOHYDRATE POLYMERS, 2017, 155 : 483 - 490
  • [37] EFFECT OF COUNTRY-OF-ORIGIN ON THE PROPERTIES OF MICROCRYSTALLINE CELLULOSE
    LANDIN, M
    MARTINEZPACHECO, R
    GOMEZAMOZA, JL
    SOUTO, C
    CONCHEIRO, A
    ROWE, RC
    INTERNATIONAL JOURNAL OF PHARMACEUTICS, 1993, 91 (2-3) : 123 - 131
  • [38] Physical and Structural Properties of Polyaniline/Microcrystalline Cellulose Nanocomposite
    Abdi, Mahnaz M.
    Liyana, Rawaida
    Tahir, Paridah Md
    Heng, Lee Yook
    Sulaiman, Yusran
    Waheeda, Nur Farhana
    Abu Hassan, Nabihah
    ADVANCED MATERIALS FOR SUSTAINABILITY AND GROWTH, 2017, 1901
  • [39] Low-temperature hydrothermal carbonization of activated carbon microsphere derived from microcrystalline cellulose as carbon dioxide (CO2) adsorbent
    Taher, T.
    Maulana, S.
    Mawaddah, N.
    Munandar, A.
    Rianjanu, A.
    Lesbani, A.
    MATERIALS TODAY SUSTAINABILITY, 2023, 23
  • [40] Preparation and Properties of Microcrystalline Cellulose from Corn Residues
    Suesat, Jantip
    Suwanruji, Potjanart
    ADVANCED TEXTILE MATERIALS, PTS 1-3, 2011, 332-334 : 1781 - +
12345