Structural aspects of tertiary amine adducts of alane and gallane

被引：40

作者：

Andrews, PC ^{[1
]}

Gardiner, MG ^{[1
]}

Raston, CL ^{[1
]}

Tolhurst, VA ^{[1
]}

机构：

[1] MONASH UNIV,DEPT CHEM,CLAYTON,VIC 3168,AUSTRALIA

来源：

INORGANICA CHIMICA ACTA | 1997年 / 259卷 / 1-2期

关键词：

crystal structures; alane adducts; gallane adducts; amine adducts;

D O I：

10.1016/S0020-1693(97)05465-0

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Structures of N-bound alane (AlH3) and gallane (GaH3) are reported: the dimethylbenzylamine adduct of gallane, [(PhCH2(Me)(2)NGaH3], which is monomeric with four-coordinate Ga, and the first chlorine containing amino complex of alane, [ClCH2CH2CH2(Me)(2)NAlH3](2), revealing that hydride bridging is favoured over Al-Cl interaction in Al obtaining a five-coordination environment. Also presented is a reinvestigation of the previously poorly defined structural determination of the trimethylamine adduct of gallane, [Me3NGaH3].

引用

页码：249 / 255

页数：7

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