Synthesis and Crystal Structural of 1,10-Phenanthroline Lead(II) Complex

被引：2

作者：

Xie, Dong ^{[1
]}

Cheng, Hua ^{[1
]}

Bi, Wen-Jie ^{[1
]}

机构：

[1] Hefei Normal Univ, Coll Chem & Chem Engn, Hefei 230601, Anhui Province, Peoples R China

来源：

ASIAN JOURNAL OF CHEMISTRY | 2014年 / 26卷 / 14期

基金：

中国国家自然科学基金;

关键词：

Lead(II) complex; 1,10-Phenanthroline; Crystal structure; BIOLOGICAL-ACTIVITY; PB(II) COMPLEXES; LIGANDS; BI(III); PHENOL; SN(II); ZN(II);

D O I：

10.14233/ajchem.2014.17453

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

A novel lead(II) complex [Pb(phen)(2)(NO3)]center dot NO3 has been synthesized, with 1,10-phenanthroline (phen) and nitrate (NO3-) as ligands and characterized by IR spectra and single-crystal X-ray diffraction measurements. The crystal is monoclinic, space group P2(1)/n with unit cell parameters: a = 16.6321(18)angstrom, b = 7.7550(8)angstrom, c = 18.0809(19)angstrom, alpha = 90 degrees, beta = 98.2880(10)degrees, gamma = 90 degrees, V = 2307.8(4)angstrom(3), Z = 4, Mr = 691.62, Dc = 1.991 Mg/cm(3), mu = 7.366 mm(-1), F(000) = 1328, T = 298(2) K, R = 0.0795, wR = 0.1980 for 4068 reflections with I > 2 sigma(I). In the molecular structure unit, lead(II) cation is coordinated by six donor atoms.

引用

页码：4535 / 4536

页数：2

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