Synthesis and Crystal Structure of a Copper(II) Complex with Benzilic Acid and 1,10-Phenanthroline

被引：0
|
作者：
谢和平
王颖
李玉林
机构：
[1] Department of Chemistry and Materials Science Hengyang Normal University
[2] Hengyang 421008 China
[3] Hengyang 421002 China
[4] Department of Chemstry and Chemical Engineering Hunan Institute of Technology
[5] Department of Chemstry and Chemical Engineering Hunan Institute of Technology
来源：
Chinese Journal of Structural Chemistry | 2008年 / 07期
关键词：
copper(II) complex; crystal structure;
D O I：
10.14102/j.cnki.0254-5861.2008.07.016
中图分类号：
O621.3 [有机合成化学];
学科分类号：
070303 ; 081704 ;
摘要：
A new complex [Cu(phen)3][(C6H5)2C(OH)COO]2·6H2O was prepared by self-assembly of benzilic acid, 1,10-phenanthroline (phen), and copper perchlorate. It crystallizes in triclinic, space group P1, with a = 1.14661(17), b = 1.6455(2), c = 1.6457(2) nm, α = 74.779(2), β = 74.904(3), γ = 84.424(3)o, V = 2.8914(7) nm3, Dc = 1.340 g/cm3, Z = 2, F(000) = 1218, GOOF = 1.018, the final R = 0.0643 and wR = 0.1633. The crystal structure shows that the copper ion is coordinated with six nitrogen atoms from six 1,10-phenanthroline molecules, forming a distorted octahedral coordination geometry.
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页码：801 / 804
页数：4
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