One-pot palladium-catalyzed phosphination of aryl iodides with Ph2PSnR3

被引：26

作者：

Martín, SE ^{[1
]}

Bonaterra, M ^{[1
]}

Rossi, RA ^{[1
]}

机构：

[1] Univ Nacl Cordoba, Fac Ciencias Quim, Dept Quim Organ, INFIQC, RA-5000 Cordoba, Argentina

来源：

JOURNAL OF ORGANOMETALLIC CHEMISTRY | 2002年 / 664卷 / 1-2期

关键词：

tertiary phosphines; palladium catalysis; P-C cross-coupling;

D O I：

10.1016/S0022-328X(02)02014-4

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

We found a very efficient one-pot phosphination reaction starting with Ph3P, which by reaction with Na metal in liquid ammonia gives Ph2P- ions that reacted with R3SnCl to afford (trialkylstannyl)diphenylphosphine. The palladium-catalyzed coupling reaction of these stannanes with aryl iodides yield functionalized phosphines in high yield (69-97%). The use of Ph3P as starting reagent, the endurance of the reaction to a wide variety of functional groups and the easiness of a one-pot reaction make this method a useful and versatile approach to tertiary phosphine oxides. (C) 2002 Elsevier Science B.V. All rights reserved.

引用

页码：223 / 227

页数：5

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