Study of the reaction of 3,6-di-tert-butyl-D3/4-benzoquinone with organozinc and organocadmium compounds

被引：5

作者：

Kurskii, Yu. A. ^{[1
]}

Druzhkov, N. O. ^{[1
]}

Egorochkin, A. N. ^{[1
]}

Abakumov, G. A. ^{[1
]}

机构：

[1] Russian Acad Sci, Razuvaev Inst Organometall Chem, Ul Tropinina 49, Nizhnii Novgorod 603950, Russia

来源：

RUSSIAN JOURNAL OF GENERAL CHEMISTRY | 2016年 / 86卷 / 01期

关键词：

o-quinone; organometallic compound; correlation analysis; polarization effect; ORGANOMETALLIC COMPOUNDS; GRIGNARD-REAGENTS; O-QUINONES; BENZOQUINONE; SCALE;

D O I：

10.1134/S1070363216010072

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The effect of substituents in the reactions of 3,6-di-tert-butyl-D3/4-benzoquinone with organozinc and organocadmium compounds, leading to three types of products: 3-alkyl-6-tert-butyl-D3/4-benzoquinones, 4-alkyl-3,6-di-tert-butyl-D3/4-benzoquinones, and 2-alkoxy-(or 2-phenoxy)-3,6-di-tert-butylphenols. Correlation analysis gave evidence to show that the first- and second-type products are formed by nucleophilic 1,2- and 1,4-addition, while substituted phenols result from single-electron transfer.

引用

页码：37 / 42

页数：6

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