Synthesis and transesterification of the complexes of methyl 2-methyl-3-trichlorostannylpropoinate with benzylmethylsulfoxide

被引：0

作者：

Tian, LJ ^{[1
]}

Shang, ZC ^{[1
]}

Yu, QS ^{[1
]}

Zhao, WN ^{[1
]}

Zhang, B ^{[1
]}

机构：

[1] Zhejiang Univ, Dept Chem, Hangzhou 310027, Peoples R China

来源：

CHINESE CHEMICAL LETTERS | 2002年 / 13卷 / 12期

关键词：

2-methyl-3-trichlorostannylpropionate complexes; solid state reaction; crystal structure; transesterification;

D O I：

暂无

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The title complex, Cl3SnCH2CH(CH3)CO2CH3.L (1), was synthesized by the reaction of methyl 2-methyl-3-trichlorostannylpropionate with benzylmcthylsulfoxide (L) in solid state at room temperature and readily underwent transesterification into the corresponding analogues Cl3SnCH2CH(CH3)CO2R.L when reacted with an alcohol ROH. The structural features of these compounds were described, and the possible mechanism or transesterification was suggested.

引用

页码：1168 / 1169

页数：2

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