Synthesis, structure and physical properties of the one-dimensional chain complex of tetrathiafulvalene carboxylate

被引：41
|
作者：
Chen Ya [1 ]
Li ChengHui [1 ]
Wang CaiFeng [1 ]
Wu Di [2 ]
Zuo JingLin [1 ]
You XiaoZeng [1 ]
机构：
[1] Nanjing Univ, State Key Lab Coordinat Chem, Sch Chem & Chem Engn, Nanjing Natl Lab Microstruct, Nanjing 210093, Peoples R China
[2] Nanjing Univ, Dept Phys, Solid State Microstruct Lab, Nanjing 210093, Peoples R China
来源：
SCIENCE IN CHINA SERIES B-CHEMISTRY | 2009年 / 52卷 / 10期
关键词：
syntheses; crystal structures; tetrathiafulvalene; cobalt complexes; BEDT-TTF; MOLECULAR MATERIALS; MAGNETIC ANIONS; BIS(ETHYLENEDITHIO)TETRASELENAFULVALENE; COMPOUND; BETS; BIS(ETHYLENEDITHIO)TETRATHIAFULVALENE; CONDUCTIVITY; FERROMAGNET; DERIVATIVES;
D O I：
10.1007/s11426-009-0237-2
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
A new Co(II) coordination polymer bearing TTF carboxylate group, [{Co-2(trioTTF)(2)(H2O)(6)}center dot 5H(2)O](n) (1) (trioTTF = 2-(5,6,8,9,11,12,14,15-octahydro-[1,3]dithiolo[4,5-h][1,4,13,7,10]trioxadithiacyclopentadecin-2-ylidene)-1,3-dithiole-4,5-dicarboxylate), has been prepared and characterized. In the structure of 1, shorter intermolecular S center dot center dot center dot center dot S contacts (3.565 angstrom) are found between the trioTTF groups from neighboring chains. The electric conductivity of 1 is poor due to the bulky crown-ether group, but it exhibits ferromagnetic interaction at low temperature.
引用
收藏
页码：1596 / 1601
页数：6
相关论文
共 50 条
  • [21] Hydrothermal Synthesis and Crystal Structure of a One-dimensional Copper(Ⅱ) Complex
    李秀梅
    王庆伟
    刘博
    结构化学, 2012, 31 (04) : 550 - 554
  • [22] Synthesis,Crystal Structure and Properties of a Novel Decavanadate Complex with One-dimensional Chain Involving Sodium and 'Bis-tris' Ligand
    许文涛
    陈莲
    江飞龙
    洪茂椿
    结构化学, 2012, 31 (03) : 401 - 407
  • [23] Synthesis, Crystal Structure and Properties of a Novel Decavanadate Complex with One-dimensional Chain Involving Sodium and 'Bis-tris' Ligand
    Xu Wen-Tao
    Chen Lian
    Jiang Fei-Long
    Hong Mao-Chun
    CHINESE JOURNAL OF STRUCTURAL CHEMISTRY, 2012, 31 (03) : 401 - 407
  • [24] Synthesis, Crystal Structure, Magnetic Property and Photo-Induced Coloration of a One-Dimensional Chain Complex
    Meng, Qingguo
    Wang, Suqing
    Zhang, Junhao
    Xun, Rui
    Chen, Mingchao
    Lu, Jitao
    CRYSTALS, 2017, 7 (03):
  • [25] Synthesis and properties of a one-dimensional mixed-ligand Cd (II) complex with helical structure
    Yu, Li-Qiong
    Huang, Ru-Dan
    Chi, Ying-Nan
    Xu, Yan-Qing
    Hu, Chang-Wen
    Journal of Beijing Institute of Technology (English Edition), 2009, 18 (01): : 79 - 83
  • [26] Synthesis, crystal structure and magnetic properties of a novel one-dimensional nickel(III) chain complex showing ferromagnetic ordering at low temperature
    Xie, JL
    Ren, XM
    Song, Y
    Zou, Y
    Meng, QJ
    JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS, 2002, (14): : 2868 - 2872
  • [27] The magnetic properties of mixed one-dimensional ferrimagnetic spin chain with complex arrangement
    Shen, Shuangjuan
    Jiang, Liqin
    Yang, Yanmin
    Feng, Qian
    Huang, Zhigao
    Zhang, Fengming
    Du, Youwei
    PHYSICA B-CONDENSED MATTER, 2007, 392 (1-2) : 141 - 146
  • [28] Hydrothermal Synthesis and Crystal Structure of a One-dimensional Copper(II) Complex
    Li Xiu-Mei
    Wang Qing-Wei
    Liu Bo
    CHINESE JOURNAL OF STRUCTURAL CHEMISTRY, 2012, 31 (04) : 550 - 554
  • [29] Hydrothermal Synthesis and Crystal Structure of a One-dimensional Cobalt(II) Complex
    Li Xiu-Mei
    Wang Qing-Wei
    Liu Bo
    CHINESE JOURNAL OF STRUCTURAL CHEMISTRY, 2012, 31 (03) : 305 - 308
  • [30] Hydrothermal Synthesis and Crystal Structure of a One-dimensional Cadmium(II) Complex
    Li Xiu-Mei
    Wang Qing-Wei
    Liu Bo
    CHINESE JOURNAL OF STRUCTURAL CHEMISTRY, 2012, 31 (07) : 965 - 970
12345