Poly[[diaquabis(μ-3,3′,5,5′-tetramethyl-4,4′-bipyrazole-κ2N:N′)cobalt(II)] dinitrate]

被引：4
|
作者：
Zhang, Guo-Fang
Lui, Hui-Qin
She, Jiang-Bo
Ng, Seik Weng [1 ]
机构：
[1] Univ Malaya, Dept Chem, Kuala Lumpur 50603, Malaysia
[2] Shaanxi Normal Univ, Sch Chem & Mat Sci, Key Lab Macromol Sci Shaanxi Prov, Xian 710062, Peoples R China
来源：
ACTA CRYSTALLOGRAPHICA SECTION E-STRUCTURE REPORTS ONLINE | 2006年 / 62卷
关键词：
D O I：
10.1107/S1600536806049257
中图分类号：
O7 [晶体学];
学科分类号：
0702 ; 070205 ; 0703 ; 080501 ;
摘要：
The Co atom in the title compound, [Co(C10H14N4)(2)(H2O)(2)]-(NO3)(2), is six-coordinate in a trans-N4O2 octahedral geometry as a consequence of bridging by the bipyrazole ligand; the bridging leads to the formation of a polycationic layer. The layers interact with the anions through hydrogen bonds, generating a three-dimensional hydrogen-bonded network. The structure is porous as 33.4% of its unit-cell volume is empty space. The Co atom lies on a special position of site symmetry 222, the bipyrazole ligand lies on a special position of site symmetry 2, the water molecule on another special position of site symmetry 2, and the nitrate anion on a special position of site symmetry m.
引用
收藏
页码：M3486 / M3488
页数：3
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