Tungsten-Containing Catalysts for Oxidative Dehydrogenation of Hydrocarbons

被引：10

作者：

Krasnobaeva, O. N. ^{[1
]}

Belomestnykh, I. P. ^{[2
]}

Isagulyants, G. V. ^{[2
]}

Kolesnikov, S. P. ^{[2
]}

Nosova, T. A. ^{[1
]}

Elizarova, T. A. ^{[1
]}

Danilov, V. P. ^{[1
]}

机构：

[1] Russian Acad Sci, NS Kurnakov Gen & Inorgan Chem Inst, Moscow 117907, Russia

[2] Russian Acad Sci, ND Zelinskii Organ Chem Inst, Moscow 117334, Russia

来源：

RUSSIAN JOURNAL OF INORGANIC CHEMISTRY | 2009年 / 54卷 / 12期

关键词：

HYDROXO SALTS; OXIDE CATALYSTS; MAGNESIUM; ALUMINUM; NICKEL; BASE;

D O I：

10.1134/S003602360912002X

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Methods for introducing tungsten into the precursors of oxide catalysts for oxidative dehydrogenation (OD) were developed. Tungsten-containing samples of oxide catalysts of various compositions were synthesized and their catalytic properties in OD of ethane were studied. The introduction of tungsten into the catalysts increased the yield of ethylene in all cases. In the series of tungsten-containing catalysts, the ethylene yield increased in the following order of the catalysis: Mg-Al-V-Mo-W-O < Mg-Al-Ni-V-Mo-W-O < MgAl-Fe-V-Mo-W < Mg-Al-Cr-V-Mo-W-O.

引用

页码：1862 / 1865

页数：4

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