Iron-Catalyzed Synthesis of Sulfur-Containing Heterocycles

被引：18

作者：

Bosset, Cyril ^{[1
]}

Lefebvre, Gauthier ^{[1
]}

Angibaud, Patrick ^{[2
]}

Stansfield, Ian ^{[2
]}

Meerpoel, Lieven ^{[3
]}

Berthelot, Didier ^{[2
]}

Guerinot, Amandine ^{[1
]}

Cossy, Janine ^{[1
]}

机构：

[1] PSL Res Univ, CNRS, Inst Chem Biol & Innovat CBI, UMR 8231,ESPCI Paris,Lab Chim Organ, 10 Rue Vauquelin, F-75231 Paris 05, France

[2] Janssen Res & Dev, Oncol Discovery Chem, Campus Maigremont CS 10615, F-27106 Val De Reuil, France

[3] Janssen Res & Dev, Janssen Pharmaceut NV Turnhoutseweg 30, B-2340 Beerse, Belgium

来源：

JOURNAL OF ORGANIC CHEMISTRY | 2017年 / 82卷 / 08期

关键词：

DIASTEREOSELECTIVE SYNTHESIS; ORGANOSULFUR COMPOUNDS; C-C; THIOMORPHOLINES; DERIVATIVES; EFFICIENT; PRECURSORS; OXATHIANE; ALCOHOLS; 1,4-OXATHIANES;

D O I：

10.1021/acs.joc.6b01827

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

An iron-catalyzed synthesis of sulfur- and sulfone-containing heterocycles is reported. The method is based on the cyclization of readily available substrates and proceeded with high efficiency and diastereoselectivity. A variety of sulfur-containing heterocycles bearing moieties suitable for subsequent functionalization are prepared. Illustrative examples of such postcyclization modifications are also presented.

引用

页码：4020 / 4036

页数：17

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