A new cadmium-organic framework fluorescent sensor for Al3+ and Ca2+ ions in aqueous medium

被引：21

作者：

Chen, Wenjie ^{[1
]}

Lin, Yanna ^{[1
]}

Zhang, Xiaoping ^{[1
]}

Xu, Na ^{[1
]}

Cheng, Peng ^{[1
]}

机构：

[1] Nankai Univ, Dept Chem, Collaborat Innovat Ctr Chem Sci & Engn, Key Lab Adv Energy Mat Chem MOE, Tianjin 300071, Peoples R China

来源：

INORGANIC CHEMISTRY COMMUNICATIONS | 2017年 / 79卷

基金：

中国国家自然科学基金;

关键词：

Cadmium-organic framework; Fluorescent sensor; Al3+ ion; Ca2+ ion; METAL-IONS; COORDINATION POLYMERS; LUMINESCENCE; EFFICIENT; ALUMINUM; COMPLEXES; CRYSTAL; CD(II); MOF;

D O I：

10.1016/j.inoche.2017.03.010

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

A new metal-organic framework (MOF), [Cd-2(bPtc)(HCOO)]center dot NH2(CH3)(2)center dot 3H(2)O (1), where H(4)bptc = 3,3',5,5'biphenyltetracarboxylic acid, was obtained by solvothermal reaction. The topology of MOF 1 is a (5,8)-connected net with {4(16) center dot 5(8) center dot 6(4)}{4(4) center dot 5(6)}(2) point symbol. MOF 1 shows high stability in aqueous solution. Luminescence study indicates that MOF 1 possesses selective turn-on luminescent sensing functions towards Al3+ and Ca2+ ions in aqueous solutions. (C) 2017 Elsevier B.V. All rights reserved.

引用

页码：29 / 32

页数：4

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