Synthesis and characterization of surfactant-encapsulated polyoxoanions:: [(CnH2n+1)2N(CH3)2]12[Mo36(NO)4O108(H2O)16] (n=12,18)

被引：0

作者：

Bu, WF

Zhang, J

Wu, LX ^{[1
]}

Tang, AC

机构：

[1] Jilin Univ, Key Lab Supramol Struct, Changchun 130023, Peoples R China

[2] Jilin Univ, Mat Minist Educ, Changchun 130023, Peoples R China

[3] Jilin Univ, State Key Lab Theoret & Computat Chem, Changchun 130023, Peoples R China

来源：

CHINESE JOURNAL OF CHEMISTRY | 2002年 / 20卷 / 12期

关键词：

surfactant; polyoxoanion; encapsulation; core-shell structure;

D O I：

暂无

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

By employing electrostatic interaction as driving force, an organic/inorganic composite with positively charged dimethyl dialkyl-chain ammonium surfactants encapsulating negatively charged (NH4)(12)[Mo-36(NO)(4)O-108(H2O)(16)].33H(2)O polyoxoanion was prepared. The structure of the novel organic/inorganic hybrid particle with hydrophilic core and hydrophobic shell in a defined stoichiometric ratio was confirmed by element analysis, H-1 NMR and FT-IR spectra. The property of the polyoxoanion was changed due to the encapsulation and it can be dissolved in organic solvent such as chloroform, benzene and toluene, but not dissolved in water.

引用

页码：1514 / 1518

页数：5

共 50 条

[41] CRYSTALLINE-STRUCTURE OF [(CH3)4N]2H2[CU2(H2O)6UMO12O42].PARA-H2O
PETRUKHINA, MA
SERGIENKO, VS
SADIKOV, GG
TATYANINA, IV
TORCHENKOVA, EA
KOORDINATSIONNAYA KHIMIYA, 1990, 16 (03): : 354 - 360
[42] Crystal structure of triaqua(4-hydroxyphthalato-κO)-(1,10-phenanthroline-κ2N,N′)]nickel(II) hydrate, Ni(H2O)3(C8H4O5)(C12H8N2) • H2O
Xiao, Bo
ZEITSCHRIFT FUR KRISTALLOGRAPHIE-NEW CRYSTAL STRUCTURES, 2012, 227 (02): : 115 - 116
[43] Crystal structure of triaqua(4-hydroxyphthalato-κO)-(1,10-phenanthroline-κ2N,N′)cobalt(II) hydrate, Co(H2O)3(C8H4O5)(C12H8N2) • H2O
Xiao, Bo
ZEITSCHRIFT FUR KRISTALLOGRAPHIE-NEW CRYSTAL STRUCTURES, 2012, 227 (02): : 125 - 126
[44] The oxidation of pyridines catalyzed by surfactant-encapsulated polyoxometalate [(C18H37)2(CH3)2N]8[HBW11O39] with the temperature-responsive property of solubility
Zhao, Wei
Yang, Chunxia
Ding, Yong
Ma, Baochun
NEW JOURNAL OF CHEMISTRY, 2013, 37 (09) : 2614 - 2618
[45] Formation of nickel(II) coordination polymers by a double betaine: [{Ni(L)(H2O)(4)}(n)]Cl-2n center dot 2nH(2)O and [{Ni(L)(2)(H2O)(2)}(n)](ClO4)(2n)center dot 4nH(2)O [L=(O2CCH2N+)-O--(CH2CH2)(3)N+CH2CO2-]
Wei, PR
Wu, DD
Wu, BM
Mak, TCW
AUSTRALIAN JOURNAL OF CHEMISTRY, 1997, 50 (01) : 85 - 90
[46] Crystal structure of (E)-N′-(4-hydroxybenzylidene)benzohydrazide monohydrate, C14H12N2N2O2•H2O
Tai, Xi-Shi
He, Yin
Feng, Yi-Min
ZEITSCHRIFT FUR KRISTALLOGRAPHIE-NEW CRYSTAL STRUCTURES, 2007, 222 (03): : 343 - 344
[47] MOLYBDENUM(VI) COMPLEXES OF BRANCHED LIGANDS WITH [N,O,O,O] AND [O,O,O] DONOR SETS - THE CRYSTAL AND MOLECULAR-STRUCTURES OF [MOO2(HOC2H4N(C2H4O)2)], [(N-C4H9)4N]2[MO2O4(O2NC(CH2O)3)2].2O2NC(CH2OH)3, [(N-C4H9)4N]2[MO2O5(HO2CCH2N(CH2CO2)2)2].H2O AND [(N-C4H9)4N][MO3O6(OCH3)(CH3C(CH2O)3)2]
LIU, SC
MA, LD
MCGOWTY, D
ZUBIETA, J
POLYHEDRON, 1990, 9 (13) : 1541 - 1553
[48] Structures that should be described in higher-symmetry, centrosymmetric space groups.: Part 2.: The structures of [Ni(C5H4NO-2-CH = N-CH2CH2-N=CH-2-C5H4NO)(H2O)2]-(ClO4)2, {Ni[C5H4NO-2-CH = N-CH(CH3)CH2-N = CH-2-C5H4NO](H2O)2}(ClO4)2, {Cu[(C5H4NO-2-CH = N-N=C(NH2)S](H2O)}2(NO3)2•H2O and {[O2CCH2NHCH2CO2Cu]•(C10H8N2)}2•12H2O
Weng, NS
Hu, SZ
CHINESE JOURNAL OF STRUCTURAL CHEMISTRY, 2000, 19 (06) : 411 - 414
[49] Hydrothermal synthesis and characterization of two mixed valence piperazine-vanadium phosphates:: (C4H12N2)(H3O)[(VOPO4)4(H2O)H2PO4]•3H2O and (C4H12N2)[(VO)(VO2)2(H2O)(PO4)2]
Do, J
Bontchev, RP
Jacobson, AJ
JOURNAL OF SOLID STATE CHEMISTRY, 2000, 154 (02) : 514 - 523
[50] Synthesis and crystal structure of (H)2[Y(H2O)8]2(NO3)8(C36H36N24O12)•13H2O
Tripolskaya, AA
Gerasko, OA
Naumov, DY
Lipkowski, J
Logvinenko, VA
Fedin, VP
JOURNAL OF STRUCTURAL CHEMISTRY, 2004, 45 (02) : 269 - 275

← 1 2 3 4 5 →