Hydride-bridged heterobimetallic complexes of zirconium and aluminum

被引：34
|
作者：
Khan, K
Raston, CL
McGrady, JE
Skelton, BW
White, AH
机构：
[1] MONASH UNIV,DEPT CHEM,MELBOURNE,VIC 3168,AUSTRALIA
[2] AUSTRALIAN NATL UNIV,DEPT CHEM,CANBERRA,ACT 0200,AUSTRALIA
[3] UNIV WESTERN AUSTRALIA,DEPT CHEM,NEDLANDS,WA 6709,AUSTRALIA
来源：
ORGANOMETALLICS | 1997年 / 16卷 / 15期
关键词：
D O I：
10.1021/om970141i
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
Treatment of [Cp2ZrCl2] with LiAlH4 and then [H3GaL] or of preformed [Cp2ZrH2] with [H3AlL] affords the heterobimetallic complexes [Cp2ZrH(mu H)(2)AlH2(L)] (L = quinuclidine (1), NMe3 (2)). Density functional calculations gives an energy of association of ''Cp2ZrH2'' and ''H3AlNH3'' of -28.8 kcal mol(-1); cf. -28.8 kcal mol(-1) for two Cp2ZrH2 units.
引用
收藏
页码：3252 / 3254
页数：3
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