Synthesis and liquid crystal properties of chiral compounds containing the core structure of 6-hydroxynicotinic acid or 4-hydroxyphenylacetic acid

被引:3
|
作者
Tsai, Wen-Liang [1 ]
Huang, Kuang-Yu [1 ]
Hsueh, Ching-Yi [1 ]
Wang, Kuan-Tung [1 ]
Wein, Chi-Chang [1 ]
Lai, Hsin-Mei [1 ]
Cheng, Pao-Swu [1 ]
机构
[1] Natl Kaohsiung Normal Univ, Dept Chem, Kaohsiung 824, Taiwan
关键词
6-hydroxynicotinic acid; 4-hydroxyphenylacetic acid; (R)-2-octanol; chiral liquid crystals; ferroelectricity; thermochromism;
D O I
10.1002/jccs.200600183
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
The carboxylic acid 4-hydroxybenzoic acid, bonded directly with (R)-2-octanol, is the core molecule of chiral liquid crystal (R)-MHPOBC. This acid was substituted either by 6-hydroxynicotinic or by 4-hydroxyphenylacetic acid. Such a structural variation induced a remarkable influence on the liquid crystal properties of (R)-MHPOBC. The series of compounds 1 similar to 4 containing 6-hydroxynicotinic acid moiety tend to exhibit a chiral smectic C (SmC*) phase, while the series of compounds 5 similar to 8 containing 4-hydroxyphenylacetic acid moiety tend to possess a chiral nematic (N*) phase.
引用
收藏
页码:1385 / 1390
页数:6
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