user

A new hydrogenation system of 4-methylstyrene using a palladinized palladium sheet electrode

被引：33
|
作者：
Iwakura, C
Yoshida, Y
Inoue, H
机构：
[1] Department of Applied Chemistry, College of Engineering, Osaka Prefecture University, Sakai
[2] Permelec Electrode Ltd., Fujisawa
来源：
JOURNAL OF ELECTROANALYTICAL CHEMISTRY | 1997年 / 431卷 / 01期
关键词：
palladinized Pd sheet; Pd black deposits; hydrogenation; active hydrogen; 4-methylstyrene;
D O I：
10.1016/S0022-0728(97)00241-6
中图分类号：
O65 [分析化学];
学科分类号：
070302 ; 081704 ;
摘要：
The deposition of Pd black on the surface of a Pd sheet electrode was carried out chemically using active hydrogen passing through the electrode, and the Pd black deposits were found to grow up three-dimensionally. The hydrogenation rate of 4-methylstyrene increased over 40 times by using the palladinized Pd sheet electrode. The increase in catalytic activity is thought to be due to the increase in reaction zone and appearance of new active sites. (C) 1997 Elsevier Science S.A.
引用
收藏
页码：43 / 45
页数：3
相关论文
共 50 条
  • [21] Hydrogenation of nitrile rubber using a new homogeneous palladium (II) catalyst. Synthesis and characterization
    Bhattacharjee, Susumita, 1600, (41): : 5 - 6
  • [22] NEW COLD SPUTTERING SYSTEM USING A TRAPPING ELECTRODE
    AOSHIMA, S
    ASAMAKI, T
    JAPANESE JOURNAL OF APPLIED PHYSICS, 1974, : 253 - 256
  • [23] Controllable hydrogenation of arylacetylenes with NaBH4 catalyzed by palladium nanoparticles in a fixed-bed system
    Zhang, Wei
    Wu, Guohao
    Wang, Ying
    Zhang, Yanhua
    TETRAHEDRON LETTERS, 2024, 152
  • [24] NEW PALLADIUM(0) AND PLATINUM(0) 4,4'-DIISOCYANOBIPHENYL MATRICES FOR HETEROGENEOUS CATALYTIC-HYDROGENATION OF ALKENES AND ALKYNES
    FEINSTEINJAFFE, I
    EFRATY, A
    JOURNAL OF MOLECULAR CATALYSIS, 1986, 35 (03): : 285 - 302
  • [25] HYDROGENATION OF IMIDAZOPHENAZINES USING PLATINUM AND PALLADIUM CATALYSTS AND A NEW SYNTHESIS OF N-2-SUBSTITUTED ANILINOAPOSAFRANINES
    OSULLIVAN, JF
    JOURNAL OF CHEMICAL RESEARCH-S, 1984, (02): : 52 - 53
  • [26] New possibilities for optimization of organic nitrocompounds electroreduction using palladium membrane electrode modified by adatoms
    Gryaznov, VM
    Manga, II
    Kondrasheva, VS
    Petrii, OA
    Tsyrlina, GA
    DOKLADY AKADEMII NAUK, 1996, 351 (04) : 485 - 488
  • [27] A new organotypic culture system of Merkel cells using epidermal sheet
    Nagase, K.
    Uchihashi, K.
    Aoki, S.
    Toda, S.
    Narisawa, Y.
    JOURNAL OF INVESTIGATIVE DERMATOLOGY, 2008, 128 : S94 - S94
  • [28] Development of new PEA system using open upper electrode
    Imai, S
    Tanaka, Y
    Fukao, T
    Takada, T
    Maeno, T
    2004 ANNUAL REPORT CONFERENCE ON ELECTRICAL INSULATION AND DIELECTRIC PHENOMENA, 2004, : 61 - 64
  • [29] SUPERIORITY OF BIPOLAR TO UNIPOLAR PACING USING A NEW ELECTRODE SYSTEM
    BREIVIK, K
    ENGEDAL, H
    OHM, OJ
    PACE-PACING AND CLINICAL ELECTROPHYSIOLOGY, 1982, 5 (02): : 298 - 298
  • [30] Transfer Hydrogenation of 4-Propylphenol Using Ethanol and Water over Charcoal-supported Palladium Catalyst
    Nagasawa, Yoshiyuki
    Nanao, Hidetaka
    Sato, Osamu
    Yamaguchi, Aritomo
    Shirai, Masayuki
    CHEMISTRY LETTERS, 2016, 45 (06) : 643 - 645
12345