Vitamin B12: An efficient type catalyst for the one-pot synthesis of 3,4,5-trisubstituted furan-2(5H)-ones and N-aryl-3-aminodihydropyrrol-2-one-4-carboxylates

被引：31
|
作者：
Kangani, Mehrnoosh [1 ]
Maghsoodlou, Malek-Taher [1 ]
Hazeri, Nourallah [1 ]
机构：
[1] Univ Sistan & Baluchestan, Fac Sci, Dept Chem, POB 98135-674, Zahedan, Iran
来源：
CHINESE CHEMICAL LETTERS | 2016年 / 27卷 / 01期
关键词：
Vitamin B12; 3,4,5-Trisubstituted furan-2(5H)-ones; N-aryl-3-aminodihydropyrrol-2-one-4-carboxylates; POLYFUNCTIONAL DIHYDROPYRROLES; MULTICOMPONENT SYNTHESIS; DERIVATIVES; INHIBITORS; FACILE; ACIDS; 2(5H)-FURANONES; RUBROLIDES; CLEAVAGE; AGENTS;
D O I：
10.1016/j.cclet.2015.07.025
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
Vitamin B12 was applied as catalyst for the one-pot three-component synthesis of 3,4,5-trisubstituted furan-2(5H)-ones from the condensation between aldehydes, amines and dialkylacetylendicarboxylates at ambient temperature in EtOH. In addition, N-aryl-3-aminodihydropyrrol-2-one-4-carboxylates were synthesised using mentioned catalyst at ambient temperature in EtOH from condensation between formaldehyde, amines, and dialkylacetylenedicarboxylates. This methodology has number of advantages such as: use of green and nonhazardous catalyst, clean work up, short reaction times, high yields and no need to column chromatography. (C) 2015 Chinese Chemical Society and Institute of Materia Medica, Chinese Academy of Medical Sciences. Published by Elsevier B.V. All rights reserved.
引用
收藏
页码：66 / 70
页数：5
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