Stereochemistry and mechanism of oxidative 1,4-addition of trifluoroacetamide to 2,3-dimethylbuta-1,3-diene

被引：9
|
作者：
Astakhova, Vera V. [1 ]
Moskalik, Mikhail Yu. [1 ]
Sterkhova, Irina V. [1 ]
Shainyan, Bagrat A. [1 ]
机构：
[1] Russian Acad Sci, Siberian Branch, AE Favorsky Irkutsk Inst Chem, Irkutsk 664033, Russia
来源：
MENDELEEV COMMUNICATIONS | 2017年 / 27卷 / 03期
基金：
俄罗斯基础研究基金会;
关键词：
CATALYTIC ASYMMETRIC AMINOHYDROXYLATION; CYCLIC DIENES; T-BUOI; OLEFINS; 1,4-DIAMINATION; AZIRIDINATION; CYCLOADDITION; FRAMEWORK; AMIDES;
D O I：
10.1016/j.mencom.2017.05.026
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
Oxidative addition of trifluoroacetamide to 2,3-dimethylbuta-1,3-diene leads to N,N'-[(2E)-2,3-dimethylbut-2-ene-1,4-diyl]bis(trifluoroacetamide) and [(2RS,3SR)-N-(2,3-dihydroxy-4-iodo-2,3-dimethylbutyl)trifluoroacetamide. A tentative mechanism is proposed.
引用
收藏
页码：293 / 295
页数：3
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