Benzyltriphenylphosphonium peroxymonosulfate: As a novel and efficient reagent for oxidation of alcohols under solvent-free conditions

被引：80
|
作者：
Hajipour, AR [1 ]
Mallakpour, SE [1 ]
Adibi, H [1 ]
机构：
[1] Isfahan Univ Technol, Coll Chem, Phermaceut Res Lab, Esfahan 84156, IR, Iran
来源：
CHEMISTRY LETTERS | 2000年 / 05期
关键词：
D O I：
10.1246/cl.2000.460
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
This paper describes the oxidation of alcohols under solvent-free conditions using benzyltriphenylphosphonium peroxymonosulfate, which has been prepared by mixing an aqueous solution of benzyltriphenylphosphonium chloride with oxone(R) at room temperature. This reagent is stable white powder, which may be stored for months without loss of its activity. This compound is readily soluble in organic solvents such as acetonitrile, chloroform, and dichloromethane and slightly soluble in carbon tetrachloride, ether, and hexane.
引用
收藏
页码：460 / 461
页数：2
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