Solvent Effect on Selective Dehydroxylation of Glycerol to 1,3-Propanediol over a Pt/WO3/ZrO2 Catalyst

被引：39

作者：

Gong Leifeng ^{[1
,3
]}

Lue Yuan ^{[1
]}

Ding Yunjie ^{[1
,2
]}

Lin Ronghe ^{[1
,3
]}

Li Jingwei ^{[1
,3
]}

Dong Wenda ^{[1
,3
]}

Wang Tao ^{[1
]}

Chen Weimiao ^{[1
]}

机构：

[1] Chinese Acad Sci, Dalian Inst Chem Phys, Dalian Natl Lab Clean Energy, Dalian 116023, Liaoning, Peoples R China

[2] Chinese Acad Sci, Dalian Inst Chem Phys, State Key Lab Catalysis, Dalian 116023, Liaoning, Peoples R China

[3] Chinese Acad Sci, Grad Univ, Beijing 100049, Peoples R China

来源：

CHINESE JOURNAL OF CATALYSIS | 2009年 / 30卷 / 12期

关键词：

platinum; tungsten oxide; zirconia; glycerol; dehydroxylation; 1,3-propanediol; solvent effect; HYDROGENOLYSIS; CONVERSION; CHEMICALS; PRODUCTS;

D O I：

10.1016/S1872-2067(08)60142-4

中图分类号：

O69 [应用化学];

学科分类号：

081704 ;

摘要：

Different solvents were studied for dehydroxylation of glycerol to 1,3-propanediol over a Pt/WO3/ZrO2 catalyst. Protic solvents such as ethanol and water favored the formation of 1,3-propanediol from glycerol. Binary solvents containing a protic component showed a synergetic solvent effect on the selective dehydroxylation of glycerol to 1,3-propanediol. The protic component in the binary solvent influenced the performance of the Pt/WO3/ZrO2 catalyst.

引用

页码：1189 / 1191

页数：3