Determination of the Flory-Huggins interaction parameter of styrene and 4-vinylpyridine using copolymer blends of poly(styrene-co-4-vinylpyridine) and polystyrene

被引：0
|
作者：
van Ekenstein, GORA
Meyboom, R
ten Brinke, G
Ikkala, O
机构：
[1] Univ Groningen, Polymer Chem Lab, NL-9747 AG Groningen, Netherlands
[2] Univ Groningen, Ctr Mat Sci, NL-9747 AG Groningen, Netherlands
[3] Helsinki Univ Technol, Phys Mat Lab, Dept Engn Phys & Math, FIN-02015 Espoo, Finland
来源：
MACROMOLECULES | 2000年 / 33卷 / 10期
关键词：
D O I：
10.1021/ma992118+
中图分类号：
O63 [高分子化学（高聚物）];
学科分类号：
070305 ; 080501 ; 081704 ;
摘要：
On the basis of the experimentally determined phase behavior in blends of polystyrene and random copolymers of styrene and 4-vinylpyridine, i.e., P(S-x-co-4VP(1-x))/PS, the Flory-Huggins interaction parameter is demonstrated to satisfy 0.30 < chi(S,4VP) less than or equal to 0.35. This value is substantially smaller than reported before. To corroborate our results, a similar study was performed using 2-vinylpyridine leading to 0.09 < chi(S,2VP) less than or equal to 0.11, in excellent agreement with the well-established value of chi(S,2VP) = 0.1.
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收藏
页码：3752 / 3756
页数：5
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