Phase diagrams and the thermodynamic Flory-Huggins interaction parameter of deformed solutions of polymers

被引：2
|
作者：
Vshivkov, S. A. [1 ]
机构：
[1] Ural State Univ, Ekaterinburg 620083, Russia
来源：
POLYMER SCIENCE SERIES A | 2009年 / 51卷 / 08期
关键词：
SHEAR-STRESS FIELD; POLY(ETHYLENE GLYCOL); POLY(VINYL ACETATE); SEPARATION; CRYSTALLIZATION;
D O I：
10.1134/S0965545X09080021
中图分类号：
O63 [高分子化学（高聚物）];
学科分类号：
070305 ; 080501 ; 081704 ;
摘要：
It is assumed that the interaction parameter used in the Flory-Huggins theory may depend on the mechanical field. The effect of deformation on phase transitions in polymer solutions is considered under this assumption. An expression relating the thermodynamic parameter of interaction between the components to deformation conditions is proposed. Quantitative relations describing shifts in liquidus lines and spinodals of polymer-solvent systems in mechanical fields are derived.
引用
下载
收藏
页码：858 / 863
页数：6
相关论文
共 50 条
  • [21] Chain connectivity and conformational variability of polymers: Clues to an adequate thermodynamic description of their solutions, 2 - Composition dependence of flory-huggins interaction parameters
    Wolf, BA
    MACROMOLECULAR CHEMISTRY AND PHYSICS, 2003, 204 (11) : 1381 - 1390
  • [22] Analysis of the Flory-Huggins interaction parameter of silicon-containing block copolymers
    Cushen, Julia D.
    Bates, Christopher M.
    Schulze, Morgan W.
    Rausch, Erica L.
    Willson, C. Grant
    Ellison, Christopher J.
    ABSTRACTS OF PAPERS OF THE AMERICAN CHEMICAL SOCIETY, 2011, 241
  • [23] Evaluation of Flory-Huggins interaction parameter from cloud points of polymer blends
    Shanghai Jiaotong Univ, Shanghai, China
    Hecheng Xiangjiao Gongye/China Synthetic Rubber Industry, 2000, 23 (02):
  • [24] Flory-huggins theory for the solubility of heterogeneously modified polymers
    Warren, Patrick B.
    MACROMOLECULES, 2007, 40 (18) : 6709 - 6712
  • [25] Measurements of the Flory-Huggins interaction parameter using a series of critical binary blends
    Nedoma, Alisyn J.
    Robertson, Megan L.
    Wanakule, Nisita S.
    Balsara, Nitash P.
    INDUSTRIAL & ENGINEERING CHEMISTRY RESEARCH, 2008, 47 (10) : 3551 - 3553
  • [26] Predicting the Flory-Huggins Parameter for Polymers with Stiffness Mismatch from Molecular Dynamics Simulations
    Kozuch, Daniel J.
    Zhang, Wenlin
    Milner, Scott T.
    POLYMERS, 2016, 8 (06)
  • [27] Liquid-Liquid Equilibria of Polymer Solutions: Flory-Huggins with Specific Interaction
    Jung, Jae Gyeong
    Bae, Young Chan
    JOURNAL OF POLYMER SCIENCE PART B-POLYMER PHYSICS, 2010, 48 (02) : 162 - 167
  • [28] GENERALIZATION OF THE FLORY-HUGGINS TREATMENT OF POLYMER SOLUTIONS.
    Kennedy, J.W.
    Gordon, M.
    Koningsveld, R.
    1972, (39): : 43 - 69
  • [29] GENERALIZATION OF FLORY-HUGGINS TREATMENT OF POLYMER-SOLUTIONS
    KENNEDY, JW
    GORDON, M
    KONINGSV.R
    JOURNAL OF POLYMER SCIENCE PART C-POLYMER SYMPOSIUM, 1972, (39): : 43 - 69
  • [30] Branched Versus Linear Polyisoprene: Flory-Huggins Interaction Parameters for their Solutions in Cyclohexane
    Eckelt, John
    Samadi, Fatemeh
    Wurm, Frederik
    Frey, Holger
    Wolf, Bernhard A.
    MACROMOLECULAR CHEMISTRY AND PHYSICS, 2009, 210 (17) : 1433 - 1439
12345