Phase diagrams and the thermodynamic Flory-Huggins interaction parameter of deformed solutions of polymers

被引：2
|
作者：
Vshivkov, S. A. [1 ]
机构：
[1] Ural State Univ, Ekaterinburg 620083, Russia
来源：
POLYMER SCIENCE SERIES A | 2009年 / 51卷 / 08期
关键词：
SHEAR-STRESS FIELD; POLY(ETHYLENE GLYCOL); POLY(VINYL ACETATE); SEPARATION; CRYSTALLIZATION;
D O I：
10.1134/S0965545X09080021
中图分类号：
O63 [高分子化学（高聚物）];
学科分类号：
070305 ; 080501 ; 081704 ;
摘要：
It is assumed that the interaction parameter used in the Flory-Huggins theory may depend on the mechanical field. The effect of deformation on phase transitions in polymer solutions is considered under this assumption. An expression relating the thermodynamic parameter of interaction between the components to deformation conditions is proposed. Quantitative relations describing shifts in liquidus lines and spinodals of polymer-solvent systems in mechanical fields are derived.
引用
收藏
页码：858 / 863
页数：6
相关论文
共 50 条
  • [1] Phase diagrams and the thermodynamic Flory-Huggins interaction parameter of deformed solutions of polymers
    S. A. Vshivkov
    [J]. Polymer Science Series A, 2009, 51 : 858 - 863
  • [2] Simple and Accurate Calibration of the Flory-Huggins Interaction Parameter
    Willis, James D.
    Beardsley, Tom M.
    Matsen, Mark W.
    [J]. MACROMOLECULES, 2020, 53 (22) : 9973 - 9982
  • [3] Characterization of the Flory-Huggins interaction parameter of polymer thermodynamics
    Russell, Travis H.
    Edwards, Brian J.
    Khomami, Bamin
    [J]. EPL, 2014, 108 (06)
  • [4] Flory-Huggins parameter of interaction in polyelectrolyle solutions of chitosan and its alkylated derivative
    Safronov, AP
    Zubarev, AY
    [J]. POLYMER, 2002, 43 (03) : 743 - 748
  • [5] Blend miscibility and the Flory-Huggins interaction parameter: A critical examination
    Tambasco, Michael
    Lipson, J. E. G.
    Higgins, Julia S.
    [J]. MACROMOLECULES, 2006, 39 (14) : 4860 - 4868
  • [6] ASYMMETRIES IN THE FLORY-HUGGINS INTERACTION PARAMETER IN ISOTOPIC POLYMER BLENDS
    LONDONO, JD
    WIGNALL, GD
    HONNELL, KG
    YETHIRAJ, A
    SCHWEIZER, KS
    [J]. ABSTRACTS OF PAPERS OF THE AMERICAN CHEMICAL SOCIETY, 1993, 206 : 321 - POLY
  • [7] Concentration dependence of the Flory-Huggins interaction parameter in aqueous solutions of capped PEO chains
    Chaudhari, M. I.
    Pratt, L. R.
    Paulaitis, M. E.
    [J]. JOURNAL OF CHEMICAL PHYSICS, 2014, 141 (24):
  • [8] CONCENTRATION-DEPENDENCE OF THE FLORY-HUGGINS PARAMETER AT DIFFERENT THERMODYNAMIC CONDITIONS
    SCHOTSCH, K
    WOLF, BA
    JEBERIEN, HE
    KLEIN, J
    [J]. MAKROMOLEKULARE CHEMIE-MACROMOLECULAR CHEMISTRY AND PHYSICS, 1984, 185 (10): : 2169 - 2181
  • [9] Composition Dependency of the Flory-Huggins Interaction Parameter in Drug-Polymer Phase Behavior
    Klueppelberg, Jana
    Handge, Ulrich A.
    Thommes, Markus
    Winck, Judith
    [J]. PHARMACEUTICS, 2023, 15 (12)
  • [10] Phase Separation in PCDTBT:PCBM Blends: from Flory-Huggins Interaction Parameters to Ternary Phase Diagrams
    Biernat, Monika
    Dąbczyński, Pawel
    Biernat, Pawel
    Rysz, Jakub
    [J]. Rysz, Jakub (jakub.rysz@uj.edu.pl), 1600, Springer Verlag (38): : 1025 - 1033
12345